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SiCl3 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Cl3Si- + Hydrogen cation = Trichlorosilane

By formula: Cl3Si- + H+ = HCl3Si

Quantity Value Units Method Reference Comment
Deltar<361.0 ± 2.4kcal/molD-EAPabst, Margrave, et al., 1977gas phase; From SiCl4. G3MP2B3 calculations indicate an EA of ca. 3.0 eV.
Quantity Value Units Method Reference Comment
Deltar<353.3 ± 2.5kcal/molH-TSPabst, Margrave, et al., 1977gas phase; From SiCl4. G3MP2B3 calculations indicate an EA of ca. 3.0 eV.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pabst, Margrave, et al., 1977
Pabst, R.E.; Margrave, J.L.; Franklin, J.L., Electron impact studies of the tetrachlorides and tetrabromides of silicon and germanium, Int. J. Mass Spectrom. Ion Phys., 1977, 25, 361. [all data]


Notes

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