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SF5 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-296.0 ± 5.3kcal/molTherLobring, Check, et al., 2003 
Deltafgas-298.9 ± 6.0kcal/molNBAELeffert, Tang, et al., 1974From SF6
Deltafgas-303.4 ± 2.5kcal/molR-EAChen, Shuie, et al., 1988From Temperature dependence of SF5-/SF6- in API attachment to SF6
Deltafgas-308.0 ± 2.3kcal/molEIAEThynne, 1972From SF6

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

F5S- + Sulfur hexafluoride = (F5S- bullet Sulfur hexafluoride)

By formula: F5S- + F6S = (F5S- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar<2.30kcal/molTDAsHiraoka, Shimizu, et al., 1995gas phase; No formation at 141 K

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

F5S- + Sulfur hexafluoride = (F5S- bullet Sulfur hexafluoride)

By formula: F5S- + F6S = (F5S- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar<2.30kcal/molTDAsHiraoka, Shimizu, et al., 1995gas phase; No formation at 141 K

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lobring, Check, et al., 2003
Lobring, K.C.; Check, C.E.; Gilbert, T.M.; Sunderlin, L.S., New measurements of the thermochemistry of SF5- and SF6-, Int. J. Mass Spectrom., 2003, 227, 3, 361-372, https://doi.org/10.1016/S1387-3806(03)00105-2 . [all data]

Leffert, Tang, et al., 1974
Leffert, C.B.; Tang, S.Y.; Rothe, E.W.; Cheng, T.C., Collisional ionization of Cs with SF6, J. Chem. Phys., 1974, 61, 4929. [all data]

Chen, Shuie, et al., 1988
Chen, E.C.M.; Shuie, L.-R.; DSa, E.D.; Batten, C.F.; Wentworth, W.E., The Negative Ion States of SF6, J. Chem. Phys., 1988, 88, 8, 4711, https://doi.org/10.1063/1.454710 . [all data]

Thynne, 1972
Thynne, J.C.J., Negative Ion Studies with a Time-of-Flight Mass Spectrometer., Dyn. Mass Spectrom., 1972, 3, 67. [all data]

Hiraoka, Shimizu, et al., 1995
Hiraoka, K.; Shimizu, A.; Minamitsu, A.; Nasu, M.; Fujimaki, S.; Yamabe, S., The small binding energies of the negative cluster ions: SF5-(SF6)1, SF6-(SF6)1 and F-(SF6)n (n=1 and 2), in the gas phase, Chem. Phys. Lett., 1995, 241, 5-6, 623, https://doi.org/10.1016/0009-2614(95)00676-U . [all data]


Notes

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