PCl2 anion
- Formula: Cl2P-
- Molecular weight: 101.880
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -146. ± 11. | kJ/mol | R-EA | Pabst, Margrave, et al., 1978 | From PCl3. G3MP2B3 calculations indicate EA = 1.70 eV |
| ΔfH°gas | <-900.0 ± 2.9 | kJ/mol | EIAE | Halmann and Klein, 1964 | From POCl3 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pabst, Margrave, et al., 1978
Pabst, R.E.; Margrave, J.L.; Franklin, J.L.,
Energy distribution in the products of ionic decomposition,
Adv. Mass Spectrom., 1978, 7, 1217. [all data]
Halmann and Klein, 1964
Halmann, M.; Klein, Y.,
Positive and Negative Ion Mass Spectra of Phosphorous Compounds,
Adv. Mass Spectrom., 1964, 3, 267. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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