cyclooctenide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

cyclooctenide anion + Hydrogen cation = Cyclooctene

By formula: C8H13- + H+ = C8H14

Quantity Value Units Method Reference Comment
Δr386.5 ± 5.1kcal/molG+TSLee and Squires, 1986gas phase; Between H2O, MeOH
Quantity Value Units Method Reference Comment
Δr379.0 ± 5.0kcal/molIMRBLee and Squires, 1986gas phase; Between H2O, MeOH

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

cyclooctenide anion + Hydrogen cation = Cyclooctene

By formula: C8H13- + H+ = C8H14

Quantity Value Units Method Reference Comment
Δr386.5 ± 5.1kcal/molG+TSLee and Squires, 1986gas phase; Between H2O, MeOH
Quantity Value Units Method Reference Comment
Δr379.0 ± 5.0kcal/molIMRBLee and Squires, 1986gas phase; Between H2O, MeOH

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lee and Squires, 1986
Lee, R.E.; Squires, R.R., Anionic homoaromaticity: A gas phase experimental study, J. Am. Chem. Soc., 1986, 105, 5078. [all data]


Notes

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