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2-methylenenorbornan-3-ide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

2-methylenenorbornan-3-ide anion + Hydrogen cation = 2-Methylenebicyclo[2.2.1]-heptane

By formula: C8H11- + H+ = C8H12

Quantity Value Units Method Reference Comment
Deltar1628.5 ± 3.6kJ/molG+TSLee and Squires, 1986gas phase; 0.4 kcal < HOH
Quantity Value Units Method Reference Comment
Deltar1599.5 ± 2.5kJ/molIMRELee and Squires, 1986gas phase; 0.4 kcal < HOH

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

2-methylenenorbornan-3-ide anion + Hydrogen cation = 2-Methylenebicyclo[2.2.1]-heptane

By formula: C8H11- + H+ = C8H12

Quantity Value Units Method Reference Comment
Deltar1628.5 ± 3.6kJ/molG+TSLee and Squires, 1986gas phase; 0.4 kcal < HOH
Quantity Value Units Method Reference Comment
Deltar1599.5 ± 2.5kJ/molIMRELee and Squires, 1986gas phase; 0.4 kcal < HOH

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lee and Squires, 1986
Lee, R.E.; Squires, R.R., Anionic homoaromaticity: A gas phase experimental study, J. Am. Chem. Soc., 1986, 105, 5078. [all data]


Notes

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