2-methylenenorborn-5-en-3-ide anion
- Formula: C8H9-
- Molecular weight: 105.1576
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C8H9- + =
By formula: C8H9- + H+ = C8H10
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 390.0 ± 2.1 | kcal/mol | G+TS | Lee and Squires, 1986 | gas phase; Ca. 1 kcal < H2O |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 383.1 ± 2.0 | kcal/mol | IMRB | Lee and Squires, 1986 | gas phase; Ca. 1 kcal < H2O |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
C8H9- + =
By formula: C8H9- + H+ = C8H10
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 390.0 ± 2.1 | kcal/mol | G+TS | Lee and Squires, 1986 | gas phase; Ca. 1 kcal < H2O |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 383.1 ± 2.0 | kcal/mol | IMRB | Lee and Squires, 1986 | gas phase; Ca. 1 kcal < H2O |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lee and Squires, 1986
Lee, R.E.; Squires, R.R.,
Anionic homoaromaticity: A gas phase experimental study,
J. Am. Chem. Soc., 1986, 105, 5078. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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