Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Mn(CO)5 anion


Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C5MnO5- + Hydrogen cation = Hydromanganese pentacarbonyl

By formula: C5MnO5- + H+ = C5HMnO5

Quantity Value Units Method Reference Comment
Deltar1301. ± 17.kJ/molIMRBMiller, Kawamura, et al., 1990gas phase; Between CCl3CO2H and HI

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C5MnO5- + Hydrogen cation = Hydromanganese pentacarbonyl

By formula: C5MnO5- + H+ = C5HMnO5

Quantity Value Units Method Reference Comment
Deltar1301. ± 17.kJ/molIMRBMiller, Kawamura, et al., 1990gas phase; Between CCl3CO2H and HI

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Miller, Kawamura, et al., 1990
Miller, A.E.S.; Kawamura, A.R.; Miller, T.M., Effects of Metal and Ligand Substitutions on Gas-Phase Acidities of Transition-Metal Hydrides, J. Am. Chem. Soc., 1990, 112, 1, 457, https://doi.org/10.1021/ja00157a075 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References