Mn(CO)5 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C5MnO5- + Hydrogen cation = Hydromanganese pentacarbonyl

By formula: C5MnO5- + H+ = C5HMnO5

Quantity Value Units Method Reference Comment
Δr311.0 ± 4.0kcal/molIMRBMiller, Kawamura, et al., 1990gas phase; Between CCl3CO2H and HI

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C5MnO5- + Hydrogen cation = Hydromanganese pentacarbonyl

By formula: C5MnO5- + H+ = C5HMnO5

Quantity Value Units Method Reference Comment
Δr311.0 ± 4.0kcal/molIMRBMiller, Kawamura, et al., 1990gas phase; Between CCl3CO2H and HI

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Miller, Kawamura, et al., 1990
Miller, A.E.S.; Kawamura, A.R.; Miller, T.M., Effects of Metal and Ligand Substitutions on Gas-Phase Acidities of Transition-Metal Hydrides, J. Am. Chem. Soc., 1990, 112, 1, 457, https://doi.org/10.1021/ja00157a075 . [all data]


Notes

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