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ClO3 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(ClO3- bullet Water) + Water = (ClO3- bullet 2Water)

By formula: (ClO3- bullet H2O) + H2O = (ClO3- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar11.7 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K
Quantity Value Units Method Reference Comment
Deltar4.70 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K

ClO3- + Hydrogen cation = HClO3

By formula: ClO3- + H+ = HClO3

Quantity Value Units Method Reference Comment
Deltar313.2 ± 3.3kcal/molIMRBMeyer and Kass, 2010gas phase
Deltar<311. ± 12.kcal/molD-EAAlekseev, Fedorova, et al., 1983gas phase; From ClO3F
Quantity Value Units Method Reference Comment
Deltar306.9 ± 3.9kcal/molH-TSMeyer and Kass, 2010gas phase

ClO3- + Water = (ClO3- bullet Water)

By formula: ClO3- + H2O = (ClO3- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar13.2 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K
Quantity Value Units Method Reference Comment
Deltar6.20 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Meyer and Kass, 2010
Meyer, M.M.; Kass, S.R., Experimental and Theoretical Gas-Phase Acidities, Bond Dissociation Energies, and Heats of Formation of HClOx, x=1-4, J. Phys. Chem. A, 2010, 114, 12, 4086-4092, https://doi.org/10.1021/jp100888k . [all data]

Alekseev, Fedorova, et al., 1983
Alekseev, V.I.; Fedorova, L.I.; Baluev, A.V., Mass Spectrometric Study of Thermochemical Characteristics of Perchloryl Fluoride and its Decomposition Product Chlorosyl Fluoride, Izv. Akad. Nauk SSR Ser. Khim. 1084, 1983. [all data]


Notes

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