D2PS


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 20002.9 gas B-X 434 654 Grimminger, Clouthier, et al., 2011


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 2 PD2 scissor 771.3 gas LF Grimminger, Clouthier, et al., 2011
3 PS stretch 448.5 gas LF Grimminger, Clouthier, et al., 2011
4 PD2 wag 637.4 gas LF Grimminger, Clouthier, et al., 2011

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 2 PD2 scissor 812 gas LF Grimminger, Clouthier, et al., 2011
3 PS stretch 612 gas LF Grimminger, Clouthier, et al., 2011
4 PD2 wag 390 gas LF Grimminger, Clouthier, et al., 2011

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Grimminger, Clouthier, et al., 2011
Grimminger, R.A.; Clouthier, D.J.; Tarroni, R., Heavy atom nitroxyl radicals. V. An experimental and ab initio study of the previously unknown H2PS free radical, J. Chem. Phys., 2011, 135, 21, 214306, https://doi.org/10.1063/1.3662416 . [all data]


Notes

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