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RbO2


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 37310 Ar Andrews, 1976

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 OO stretch 1111.3 Ar Ra IR Smardzewski and Andrews, 1973
Andrews, Hwang, et al., 1973
2 ORbO s-stretch 255.0 Ar IR Andrews, 1971
Andrews, Hwang, et al., 1973
b2 3 ORbO a-stretch 282.5 w Ar IR Andrews, Hwang, et al., 1973

Notes

wWeak
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Andrews, 1976
Andrews, L., Ultraviolet absorption studies of the alkali metal atom-oxygen molecule matrix reaction, J. Mol. Spectrosc., 1976, 61, 3, 337, https://doi.org/10.1016/0022-2852(76)90324-6 . [all data]

Smardzewski and Andrews, 1973
Smardzewski, R.R.; Andrews, L., Raman spectra of the products of rubidium and cesium atom argon matrix reactions with oxygen molecules, J. Phys. Chem., 1973, 77, 6, 801, https://doi.org/10.1021/j100625a013 . [all data]

Andrews, Hwang, et al., 1973
Andrews, L.; Hwang, J.-T.; Trindle, C., Matrix reactions of cesium atoms with oxygen molecules. Infrared spectrum and vibrational analysis of cesium superoxide (Cs+O2-). Infrared observation of cesium peroxide (Cs+O22-Cs+) and cesium disuperoxide (Cs+O4-). Theoretical structure of alkali metal oxides (M+O4-), J. Phys. Chem., 1973, 77, 8, 1065, https://doi.org/10.1021/j100627a020 . [all data]

Andrews, 1971
Andrews, L., Matrix Reactions of K and Rb Atoms with Oxygen Molecules, J. Chem. Phys., 1971, 54, 11, 4935, https://doi.org/10.1063/1.1674772 . [all data]


Notes

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