HAsO


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 15316.67 gas A-X 525 846 Grimminger and Clouthier, 2011


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 2 Bend 599.4 gas LF Grimminger and Clouthier, 2011
3 AsO stretch 644.9 gas LF Grimminger and Clouthier, 2011

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 AsH stretch 1931.0 T Ar IR Andrews, Withnall, et al., 1989
2 Bend 832.4 gas LF Grimminger and Clouthier, 2011
3 AsO stretch 937 gas LF Grimminger and Clouthier, 2011

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Grimminger and Clouthier, 2011
Grimminger, R.; Clouthier, D.J., The electronic spectrum of the previously unknown HAsO transient molecule, J. Chem. Phys., 2011, 135, 18, 184308, https://doi.org/10.1063/1.3658645 . [all data]

Andrews, Withnall, et al., 1989
Andrews, L.; Withnall, R.; Moores, B.W., Infrared spectra of arsine-ozone complexes, reaction products, and photolysis products in solid argon, J. Phys. Chem., 1989, 93, 4, 1279, https://doi.org/10.1021/j100341a022 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References