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CH2COCH3-


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 14095 ± 16 gas Zimmerman, Reed, et al., 1977
Ellison, Engleking, et al., 1982
Brinkman, Berger, et al., 2001
Alconcel, Deyerl, et al., 2001
Yacovitch, Garand, et al., 2010
Ichino, Villano, et al., 2011

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 13 OCC bend 500 ± 30 gas PE Ichino, Villano, et al., 2011
14 CCC bend 420 ± 15 gas PE Ichino, Villano, et al., 2011

Notes

dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zimmerman, Reed, et al., 1977
Zimmerman, A.H.; Reed, K.J.; Brauman, J.I., Photodetachment of electrons from enolate anions. Gas phase electron affinities of enolate radicals, J. Am. Chem. Soc., 1977, 99, 7203. [all data]

Ellison, Engleking, et al., 1982
Ellison, G.B.; Engleking, P.C.; Lineberger, W.C., Photoelectron spectroscopy of alkoxide and enolate negative ions, J. Phys. Chem., 1982, 86, 4873. [all data]

Brinkman, Berger, et al., 2001
Brinkman, E.A.; Berger, S.; Marks, J.; Brauman, J.I., J. Chem. Phys., 2001, 99, 12675. [all data]

Alconcel, Deyerl, et al., 2001
Alconcel, L.S.; Deyerl, H.-J.; Continetti, R.E., Effects of Alkyl Substitution on the Energetics of Enolate Anions and Radicals, J. Am. Chem. Soc., 2001, 123, 50, 12675, https://doi.org/10.1021/ja0120431 . [all data]

Yacovitch, Garand, et al., 2010
Yacovitch, T.I.; Garand, E.; Neumark, D.M., Slow Photoelectron Velocity-Map Imaging of the, J. Phys. Chem. A, 2010, 114, 42, 11091, https://doi.org/10.1021/jp101930b . [all data]

Ichino, Villano, et al., 2011
Ichino, T.; Villano, S.M.; Gianola, A.J.; Goebbert, D.J.; Velarde, L.; Sanov, A., et al., Photoelectron Spectroscopic Study of the Oxyallyl Diradical, J. Phys. Chem. A, 2011, 115, 9, 1634, https://doi.org/10.1021/jp111311k . [all data]


Notes

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