bicyc-C6H3F2N

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 39700 Ar Morawietz and Sander, 1996

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
C=N stretch 1679.3 m Ar IR Morawietz and Sander, 1996
C=C stretch 1609.8 vs Ar IR Morawietz and Sander, 1996
C=C stretch 1519.7 m Ar IR Morawietz and Sander, 1996
1412.2 m s Ar IR Morawietz and Sander, 1996
C-C stretch 1318.0 m Ar IR Morawietz and Sander, 1996
CF stretch 1258.9 s Ar IR Morawietz and Sander, 1996
CF stretch 1179.7 s Ar IR Morawietz and Sander, 1996
6-ring deform. 1138.3 m Ar IR Morawietz and Sander, 1996
6-ring deform. 1006.7 w m Ar IR Morawietz and Sander, 1996
6-ring OPLA 939.2 m Ar IR Morawietz and Sander, 1996
CH OPLA 896.1 w Ar IR Morawietz and Sander, 1996
3-ring deform. 856.9 w m Ar IR Morawietz and Sander, 1996
796.0 m Ar IR Morawietz and Sander, 1996
737.4 w m Ar IR Morawietz and Sander, 1996
688.2 w m Ar IR Morawietz and Sander, 1996
608.5 w Ar IR Morawietz and Sander, 1996
557.1 w Ar IR Morawietz and Sander, 1996
535.7 w Ar IR Morawietz and Sander, 1996
500.3 w Ar IR Morawietz and Sander, 1996
430.0 w Ar IR Morawietz and Sander, 1996

Additional references: Jacox, 1998, page 361

Notes

wWeak
mMedium
sStrong
vsVery strong
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Morawietz and Sander, 1996
Morawietz, J.; Sander, W., Photochemistry of Fluorinated Phenyl Nitrenes: Matrix Isolation of Fluorinated Azirines, J. Org. Chem., 1996, 61, 13, 4351, https://doi.org/10.1021/jo960093w . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Notes

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