CuSH


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 23053.5 gas B-X 411 444 Kokkin, Reilly, et al., 2011


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 2 Bend 484 gas MPI Kokkin, Reilly, et al., 2011
3 CuS stretch 355 gas MPI Kokkin, Reilly, et al., 2011

State:   A


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 19543.55 ± 0.04 gas A-X 470 515 Sunahori, Zhang, et al., 2006


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 3 CuS stretch 334 gas LF Sunahori, Zhang, et al., 2006

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 3 CuS stretch 396 gas LF Sunahori, Zhang, et al., 2006

Additional references: Janczyk, Walter, et al., 2005

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kokkin, Reilly, et al., 2011
Kokkin, D.L.; Reilly, N.J.; McCarthy, M.C.; Stanton, J.F., Experimental and theoretical investigation of the electronic transition of CuSH, J. Mol. Spectrosc., 2011, 268, 1-2, 23, https://doi.org/10.1016/j.jms.2011.03.023 . [all data]

Sunahori, Zhang, et al., 2006
Sunahori, F.X.; Zhang, X.; Clouthier, D.J., The electronic spectrum of jet-cooled copper hydrosulfide (CuSH), J. Chem. Phys., 2006, 125, 8, 084310, https://doi.org/10.1063/1.2338321 . [all data]

Janczyk, Walter, et al., 2005
Janczyk, A.; Walter, S.K.; Ziurys, L.M., Examining the transition metal hydrosulfides: the pure rotational spectrum of CuSH, Chem. Phys. Lett., 2005, 401, 1-3, 212, https://doi.org/10.1016/j.cplett.2004.10.146 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References