OCS+2

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   1Π
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 61800 ± 800 gas Eland, 2003
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 3 CS stretch 682 ± 10 gas PE Eland, 2003

State:   3Π
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 57100 ± 800 gas Eland, 2003
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 3 CS stretch 775 ± 10 gas PE Eland, 2003

Additional references: Hall, Avaldi, et al., 1994

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Eland, 2003
Eland, J.H.D., Complete double photoionisation spectra of small molecules from TOF-PEPECO measurements, Chem. Phys., 2003, 294, 2, 171, https://doi.org/10.1016/j.chemphys.2003.08.001 . [all data]

Hall, Avaldi, et al., 1994
Hall, R.I.; Avaldi, L.; Dawber, G.; McConkey, A.G.; MacDonald, M.A.; King, G.C., Double photoionization of CO2, OCS, C2H2, CF4, and C6H6 studied by threshold photoelectrons coincidence (TPEsCO) spectroscopy, Chem. Phys., 1994, 187, 1-2, 125, https://doi.org/10.1016/0301-0104(94)00188-X . [all data]

Notes

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