Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

c-HCSSH


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 3 HCS deform. 1255.5 gas IR Ioannoni, Moule, et al., 1989
3 HCS deform. 1265.4 Ar IR Bohn, Brabson, et al., 1992
4 C=S stretch 1080.8 gas IR Ioannoni, Moule, et al., 1989
4 C=S stretch 1082.2 Ar IR Bohn, Brabson, et al., 1992
5 925.5 Ar IR Bohn, Brabson, et al., 1992
6 C-S stretch 710.0 gas IR Ioannoni, Moule, et al., 1989
6 C-S stretch 725.8 Ar IR Bohn, Brabson, et al., 1992
a 8 C=S OPLA 794.5 gas IR Ioannoni, Moule, et al., 1989
8 C=S OPLA 807.2 Ar IR Bohn, Brabson, et al., 1992

Additional references: Jacox, 1994, page 259; Bak, Nielsen, et al., 1978; Bak, Nielsen, et al., 1979


References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ioannoni, Moule, et al., 1989
Ioannoni, F.; Moule, D.C.; Goddard, J.D.; Clouthier, D.J., Thiocarbonyl spectroscopy: the infrared spectrum and ab initio vibrational frequencies of cis- and trans-dithioformic acid in the X1A´ ground state, J. Mol. Struct., 1989, 197, 159, https://doi.org/10.1016/0022-2860(89)85159-2 . [all data]

Bohn, Brabson, et al., 1992
Bohn, R.B.; Brabson, G.D.; Andrews, L., Reaction of atomic hydrogen and carbon disulfide: infrared spectra of HSCS and HSHCS in solid argon, J. Phys. Chem., 1992, 96, 4, 1582, https://doi.org/10.1021/j100183a019 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Bak, Nielsen, et al., 1978
Bak, B.; Nielsen, O.J.; Svanholt, H., Production and microwave spectra of dithioformic acid, HCSSH, J. Mol. Spectrosc., 1978, 69, 3, 401, https://doi.org/10.1016/0022-2852(78)90233-3 . [all data]

Bak, Nielsen, et al., 1979
Bak, B.; Nielsen, O.; Svanholt, H.; Christiansen, J.J., Rotational spectra of isotopic di-thioformic acids with a structure of trans HCSSH, J. Mol. Spectrosc., 1979, 75, 1, 134, https://doi.org/10.1016/0022-2852(79)90154-1 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References