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c-CH2(NO)OH


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 OH stretch 3477 m Ar IR Muller and Huber, 1983
Muller, Huber, et al., 1984
Jacox, 1984
2 CH stretch 2906 w Ar IR Muller, Huber, et al., 1984
3 N=O stretch 1559 w m Ar IR Muller and Huber, 1983
Muller, Huber, et al., 1984
4 CH2 scissors 1439 m Ar IR Muller, Huber, et al., 1984
5 COH bend 1355 m Ar IR Muller, Huber, et al., 1984
Jacox, 1984
6 CH2 wag 1250 w m Ar IR Muller, Huber, et al., 1984
7 C-O stretch 1130 vs Ar IR Muller and Huber, 1983
Muller, Huber, et al., 1984
Jacox, 1984
8 (Mixed) 792 m Ar IR Muller, Huber, et al., 1984
9 Skel. deform. 755 w m Ar IR Muller, Huber, et al., 1984
10 Skel. deform. 334 w Ar IR Muller, Huber, et al., 1984
a 11 CH stretch 2916 w Ar IR Muller, Huber, et al., 1984
12 CH2 twist 1202 w Ar IR Muller, Huber, et al., 1984
13 CH2 rock 888 w Ar IR Muller, Huber, et al., 1984
14 OH torsion 346 w m Ar IR Muller, Huber, et al., 1984
15 NO torsion 191 w m Ar IR Muller, Huber, et al., 1984

Additional references: Jacox, 1994, page 367

Notes

wWeak
mMedium
vsVery strong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Muller and Huber, 1983
Muller, R.P.; Huber, J.R., Reversible, light-induced isomerization of matrix-isolated molecules. Nitrosomethanol, J. Phys. Chem., 1983, 87, 14, 2460, https://doi.org/10.1021/j100237a004 . [all data]

Muller, Huber, et al., 1984
Muller, R.P.; Huber, J.R.; Hollenstein, H., Photochemical preparation of nitrosomethanol: Vibrational frequencies, force field, and normal coordinate analysis of the cis and trans isomers, J. Mol. Spectrosc., 1984, 104, 2, 209, https://doi.org/10.1016/0022-2852(84)90116-4 . [all data]

Jacox, 1984
Jacox, M.E., Photodecomposition of nitromethane trapped in solid argon, J. Phys. Chem., 1984, 88, 15, 3373, https://doi.org/10.1021/j150659a047 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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