CD3HgD


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CD3 stretch 2127.7 w Ar IR Legay-Sommaire and Legay, 1994
Greene, Andrews, et al., 1995
2 HgD stretch 1400.7 vs Ar IR Legay-Sommaire and Legay, 1994
Greene, Andrews, et al., 1995
2 HgD stretch 1402.6 N2 IR Legay-Sommaire and Legay, 1996
3 CD3 deform. 1024.5 w T Ar IR Legay-Sommaire and Legay, 1994
4 HgC stretch 487.0 Ar IR Greene, Andrews, et al., 1995
4 HgC stretch 485.6 N2 IR Legay-Sommaire and Legay, 1996
e 5 CD3 stretch 2233.9 m Ar IR Legay-Sommaire and Legay, 1994
6 CD3 deform. 1041.1 w T Ar IR Legay-Sommaire and Legay, 1994
Greene, Andrews, et al., 1995
7 CD3 rock 593.5 m Ar IR Legay-Sommaire and Legay, 1994
Greene, Andrews, et al., 1995
7 CD3 rock 592.1 Ar IR Legay-Sommaire and Legay, 1994
Greene, Andrews, et al., 1995
7 CD3 rock 592.8 N2 IR Legay-Sommaire and Legay, 1996
7 CD3 rock 589.3 N2 IR Legay-Sommaire and Legay, 1996
8 CHgD deform. 374.5 Ar IR Greene, Andrews, et al., 1995

Notes

wWeak
mMedium
vsVery strong
TTentative assignment or approximate value

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Legay-Sommaire and Legay, 1994
Legay-Sommaire, N.; Legay, F., Photochemical formation of CH3HgH in Hg/CH4/Ar matrices studied by FTIR spectroscopy, Chem. Phys. Lett., 1994, 217, 1-2, 97, https://doi.org/10.1016/0009-2614(93)E1367-P . [all data]

Greene, Andrews, et al., 1995
Greene, T.M.; Andrews, L.; Downs, A.J., The Reaction of Zinc, Cadmium, and Mercury Atoms with Methane: Infrared Spectra of the Matrix-Isolated Methylmetal Hydrides, J. Am. Chem. Soc., 1995, 117, 31, 8180, https://doi.org/10.1021/ja00136a015 . [all data]

Legay-Sommaire and Legay, 1996
Legay-Sommaire, N.; Legay, F., Isotope effects in the photochemical formation of HHgCH3 and DHgCD3 in nitrogen and methane matrices, Chem. Phys., 1996, 211, 1-3, 367, https://doi.org/10.1016/0301-0104(96)00190-5 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References