Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

PD3F2


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a2 3 PD3 deform. 936 m gas IR Beckers, 1993
4 PF2 a-stretch 745 vs gas IR Beckers, 1993
4 PF2 a-stretch 749 Ar IR Andrews and Withnall, 1989
e' 5 PD3 a-stretch 1828 s gas IR Beckers, 1993
6 PD3 deform. 719 Ar IR Andrews and Withnall, 1989
7 PF2 deform. 319 m gas IR Beckers, 1993

Notes

mMedium
sStrong
vsVery strong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Beckers, 1993
Beckers, H., Eine neue Synthese von H3PF2 durch selektive Fluorierung von H3P. Schwingungsspektren und Normalkoordinatenanalyse der Reihe HnD3?nPF2, Z. Anorg. Allg. Chem., 1993, 619, 11, 1869, https://doi.org/10.1002/zaac.19936191110 . [all data]

Andrews and Withnall, 1989
Andrews, L.; Withnall, R., Cocondensation reaction between phosphine and fluorine: matrix infrared spectra of difluorophosphorane, difluorophosphine and fluorophosphine, Inorg. Chem., 1989, 28, 3, 494, https://doi.org/10.1021/ic00302a023 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References