cyc-Ga2D2


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

ag 1 860 ± 5 Ar IR Himmel, Manceron, et al., 2002
2 176.1 Ar IR Ra Himmel, Manceron, et al., 2002
Kohn, Himmel, et al., 2003
b2g 3 638.4 Ar IR Himmel, Manceron, et al., 2002, 2
Himmel, Manceron, et al., 2002
b1u 4 GaD stretch 751.9 Ne IR Wang and Andrews, 2003
4 GaD stretch 728.2 Ar IR Xiao, Hauge, et al., 1993
Himmel, Manceron, et al., 2002, 2
Himmel, Manceron, et al., 2002
Kohn, Himmel, et al., 2003
Wang and Andrews, 2003
4 GaD stretch 732.0 Kr IR Xiao, Hauge, et al., 1993
4 GaD stretch 749.0 D2 IR Wang and Andrews, 2003
b2u 5 653.6 Ar IR Himmel, Manceron, et al., 2002, 2
Himmel, Manceron, et al., 2002


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Himmel, Manceron, et al., 2002
Himmel, H.-J.; Manceron, L.; Downs, A.J.; Pullumbi, P., Formation and Characterization of the Gallium and Indium Subhydride Molecules Ga, J. Am. Chem. Soc., 2002, 124, 16, 4448, https://doi.org/10.1021/ja0122795 . [all data]

Kohn, Himmel, et al., 2003
Kohn, A.; Himmel, H.-J.; Gaertner, B., Why Does a Ga2 Dimer React Spontaneously with H2, but a Ga Atom Does Not?---A Detailed Quantum Chemical Investigation of the Differences in Reactivity Between Ga Atoms and Ga2 Dimers, in Combination with Experimental Results, Chem. Eur. J., 2003, 9, 16, 3909, https://doi.org/10.1002/chem.200204633 . [all data]

Himmel, Manceron, et al., 2002, 2
Himmel, H.-J.; Manceron, L.; Downs, A.J.; Pullumbi, P., Characterization and Photochemistry of the Gallium and Indium Subhydrides Ga2H2 and In2H2 This work was supported by the Deutsche Forschungsgemeinschaft (Habilitation grant to H.-J. H.), the CNRS (L. M.), and the EPSRC (A. J. D.)., Angew. Chem. Int. Ed., 2002, 41, 5, 796, https://doi.org/10.1002/1521-3773(20020301)41:5<796::AID-ANIE796>3.0.CO;2-3 . [all data]

Wang and Andrews, 2003
Wang, X.; Andrews, L., Infrared Spectra of Gallium Hydrides in Solid Hydrogen: GaH, J. Phys. Chem. A, 2003, 107, 51, 11371, https://doi.org/10.1021/jp035393d . [all data]

Xiao, Hauge, et al., 1993
Xiao, Z.L.; Hauge, R.H.; Margrave, J.L., Cryogenic reactions of gallium with molecular hydrogen and methane, Inorg. Chem., 1993, 32, 5, 642, https://doi.org/10.1021/ic00057a026 . [all data]


Notes

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