t-DOCO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 OD stretch 2684.10 gas LD Petty and Moore, 1993
1 OD stretch 2678.1 w m Ne IR Forney, Jacox, et al., 2003
1 OD stretch 2637.5 N2 IR Mielke, Olbert-Majkut, et al., 2003
1 OD stretch 2558 CO IR Milligan and Jacox, 1971
2 C=O stretch 1851.65 gas DL Sears, Fawzy, et al., 1992
2 C=O stretch 1846.2 s Ne IR Forney, Jacox, et al., 2003
2 C=O stretch 1841.7 Ar IR Jacox, 1988
2 C=O stretch 1837.2 N2 IR Mielke, Olbert-Majkut, et al., 2003
2 C=O stretch 1825 CO IR Milligan and Jacox, 1971
3 Mixed 1081 ± 10 gas PE Johnson, Poad, et al., 2011
3 Mixed 1082.6 m Ne IR Forney, Jacox, et al., 2003
3 Mixed 1092.6 Ar IR Jacox, 1988
3 Mixed 1109.3 N2 IR Mielke, Olbert-Majkut, et al., 2003
3 Mixed 1117 CO IR Milligan and Jacox, 1971
5 OCO bend 597 ± 5 gas PE Johnson, Poad, et al., 2011
5 OCO bend 610 m CO IR Milligan and Jacox, 1971
a 6 Torsion 472 w m CO IR Milligan and Jacox, 1971

Notes

wWeak
mMedium
sStrong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Petty and Moore, 1993
Petty, J.T.; Moore, C.B., Transient infrared absorption spectrum of the ν1 fundamental of trans-DOCO, J. Chem. Phys., 1993, 99, 1, 47, https://doi.org/10.1063/1.465773 . [all data]

Forney, Jacox, et al., 2003
Forney, D.; Jacox, M.E.; Thompson, W.E., Infrared spectra of trans-HOCO, HCOOH[sup +], and HCO[sub 2][sup -] trapped in solid neon, J. Chem. Phys., 2003, 119, 20, 10814, https://doi.org/10.1063/1.1621382 . [all data]

Mielke, Olbert-Majkut, et al., 2003
Mielke, Z.; Olbert-Majkut, A.; Tokhadze, K.G., Photolysis of the OC...HONO complex in low temperature matrices: Infrared detection and ab initio calculations of nitrosoformic acid, HOC(O)NO, J. Chem. Phys., 2003, 118, 3, 1364, https://doi.org/10.1063/1.1528897 . [all data]

Milligan and Jacox, 1971
Milligan, D.E.; Jacox, M.E., Infrared Spectrum and Structure of Intermediates in the Reaction of OH with CO, J. Chem. Phys., 1971, 54, 3, 927, https://doi.org/10.1063/1.1675022 . [all data]

Sears, Fawzy, et al., 1992
Sears, T.J.; Fawzy, W.M.; Johnson, P.M., Transient diode laser absorption spectroscopy of the ν2 fundamental of trans-HOCO and DOCO, J. Chem. Phys., 1992, 97, 6, 3996, https://doi.org/10.1063/1.462939 . [all data]

Jacox, 1988
Jacox, M.E., The vibrational spectrum of the t-HOCO free radical trapped in solid argon, J. Chem. Phys., 1988, 88, 8, 4598, https://doi.org/10.1063/1.453772 . [all data]

Johnson, Poad, et al., 2011
Johnson, C.J.; Poad, M.E. Harding.B.L.J.; Stanton, J.F.; Continetti, R.E., Electron Affinities, Well Depths, and Vibrational Spectroscopy of, J. Am. Chem. Soc., 2011, 133, 49, 19606, https://doi.org/10.1021/ja207724f . [all data]

Notes

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