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DCBr2


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 2 CBr s-stretch 616 w Ar IR Carver and Andrews, 1969
170 ± 40 gas PE Vogelhuber, Wren, et al., 2011
a 5 DCBr deform. 898 vs Ar IR Carver and Andrews, 1969
Andrews, Wight, et al., 1978
Andrews, Prochaska, et al., 1979
6 CBr a-stretch 725 s Ar IR Carver and Andrews, 1969
Andrews, Wight, et al., 1978
Andrews, Prochaska, et al., 1979

Notes

wWeak
sStrong
vsVery strong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Carver and Andrews, 1969
Carver, T.G.; Andrews, L., Matrix Infrared Spectrum and Bonding in the Dibromomethyl Radical, J. Chem. Phys., 1969, 50, 10, 4223, https://doi.org/10.1063/1.1670887 . [all data]

Vogelhuber, Wren, et al., 2011
Vogelhuber, K.M.; Wren, S.W.; McCoy, A.B.; Ervin, K.M.; Lineberger, W.C., Photoelectron spectra of dihalomethyl anions: Testing the limits of normal mode analysis, J. Chem. Phys., 2011, 134, 18, 184306, https://doi.org/10.1063/1.3585606 . [all data]

Andrews, Wight, et al., 1978
Andrews, L.; Wight, C.A.; Prochaska, F.T.; McDonald, S.A.; Ault, B.S., Vacuum-ultraviolet photoionization of bromoform and its chlorine substituted counterparts during condensation with argon at 15 K, J. Mol. Spectrosc., 1978, 73, 1, 120, https://doi.org/10.1016/0022-2852(78)90199-6 . [all data]

Andrews, Prochaska, et al., 1979
Andrews, L.; Prochaska, F.T.; Ault, B.S., Matrix photoionization and radiolysis of dichloromethane and dibromomethane. Infrared and ultraviolet absorption spectra and photolysis of CH2Cl2+ and CH2Br2+, J. Am. Chem. Soc., 1979, 101, 1, 9, https://doi.org/10.1021/ja00495a002 . [all data]


Notes

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