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C6D5O


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 25240 ± 10 Ar C-X 349 397 Pullin and Andrews, 1982
Spanget-Larsen, Gil, et al., 2001


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

1349 ± 20 Ar AB Pullin and Andrews, 1982
809 ± 20 Ar AB Pullin and Andrews, 1982

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 15973 ± 10 Ar Radziszewski, Gil, et al., 2001

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 7661 gas A-X 1165 1306 Cheng, Witek, et al., 2008


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a2 12 772 ± 2 gas CR Cheng, Witek, et al., 2008
13 626 ± 3 gas CR Cheng, Witek, et al., 2008
14 365 ± 2 gas CR Cheng, Witek, et al., 2008
b1 15 812 ± 7 gas CR Cheng, Witek, et al., 2008
17 599 ± 2 gas CR Cheng, Witek, et al., 2008
18 532 ± 2 gas CR Cheng, Witek, et al., 2008
19 436 ± 5 gas CR Cheng, Witek, et al., 2008

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CD stretch 2331 w Ar IR Spanget-Larsen, Gil, et al., 2001
2 CD stretch 2298 w Ar IR Spanget-Larsen, Gil, et al., 2001
3 CD stretch 2284 w Ar IR Spanget-Larsen, Gil, et al., 2001
4 CC stretch 1509 s Ar IR Spanget-Larsen, Gil, et al., 2001
5 CO stretch 1467 m s Ar IR Spanget-Larsen, Gil, et al., 2001
6 Mixed 1244 w m Ar IR Spanget-Larsen, Gil, et al., 2001
7 CCC bend 944 w Ar IR Spanget-Larsen, Gil, et al., 2001
8 Mixed 902 w Ar IR Spanget-Larsen, Gil, et al., 2001
9 CD bend 844 w Ar IR Spanget-Larsen, Gil, et al., 2001
10 Mixed 724 w Ar IR Spanget-Larsen, Gil, et al., 2001
11 CCC bend 505 w Ar IR Spanget-Larsen, Gil, et al., 2001
b1 15 DCCD torsion 860 w Ar IR Spanget-Larsen, Gil, et al., 2001
16 Mixed 775 w m Ar IR Spanget-Larsen, Gil, et al., 2001
17 Mixed 660 m Ar IR Spanget-Larsen, Gil, et al., 2001
18 Mixed 489 s Ar IR Spanget-Larsen, Gil, et al., 2001
19 Mixed 406 w Ar IR Spanget-Larsen, Gil, et al., 2001
b2 21 CD stretch 2326 w Ar IR Spanget-Larsen, Gil, et al., 2001
22 CD stretch 2281 w Ar IR Spanget-Larsen, Gil, et al., 2001
23 Mixed 1449 w m Ar IR Spanget-Larsen, Gil, et al., 2001
24 Mixed 1334 w m Ar IR Spanget-Larsen, Gil, et al., 2001
25 Mixed 1255 m Ar IR Spanget-Larsen, Gil, et al., 2001
26 Mixed 1032 w Ar IR Spanget-Larsen, Gil, et al., 2001
27 Mixed 836 w Ar IR Spanget-Larsen, Gil, et al., 2001
28 Mixed 824 w Ar IR Spanget-Larsen, Gil, et al., 2001
30 CO bend 423 w Ar IR Spanget-Larsen, Gil, et al., 2001

Notes

wWeak
mMedium
sStrong
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pullin and Andrews, 1982
Pullin, D.; Andrews, L., The absorption spectra of the phenoxyl radical in solid argon, J. Mol. Struct., 1982, 95, 181, https://doi.org/10.1016/0022-2860(82)90143-0 . [all data]

Spanget-Larsen, Gil, et al., 2001
Spanget-Larsen, J.; Gil, M.; Gorski, A.; Blake, D.M.; Waluk, J.; Radziszewski, J.G., Vibrations of the Phenoxyl Radical, J. Am. Chem. Soc., 2001, 123, 45, 11253, https://doi.org/10.1021/ja0113596 . [all data]

Radziszewski, Gil, et al., 2001
Radziszewski, J.G.; Gil, M.; Gorski, A.; Spanget-Larsen, J.; Waluk, J.; Mroz, B.J., Electronic states of the phenoxyl radical, J. Chem. Phys., 2001, 115, 21, 9733, https://doi.org/10.1063/1.1415465 . [all data]

Cheng, Witek, et al., 2008
Cheng, C.-W.; Witek, H.; Lee, Y.-P., Rovibronic bands of the A [sup 2]B[sub 2]<--X [sup 2]B[sub 1] transition of C[sub 6]H[sub 5]O and C[sub 6]D[sub 5]O detected with cavity ringdown absorption near 1.2 «mu»m, J. Chem. Phys., 2008, 129, 15, 154307, https://doi.org/10.1063/1.2992077 . [all data]


Notes

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