CD2CDO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 28840 gas B-X 300 411 Inoue and Akimoto, 1981
Osborn, Choi, et al., 1997
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 980 gas LF Inoue and Akimoto, 1981
768 gas LF Inoue and Akimoto, 1981

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' C=O stretch 1540 gas LF Inoue and Akimoto, 1981
C=O stretch 1513 m s H Ar IR Jacox, 1982
1223 w H Ar IR Jacox, 1982
CC stretch 1050 gas LF Inoue and Akimoto, 1981
CCO bend 445 gas LF Inoue and Akimoto, 1981

Notes

wWeak
mMedium
sStrong
H(1/2)(2ν)
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Inoue and Akimoto, 1981
Inoue, G.; Akimoto, H., Laser-induced fluorescence of the C2H3O radical, J. Chem. Phys., 1981, 74, 1, 425, https://doi.org/10.1063/1.440848 . [all data]

Osborn, Choi, et al., 1997
Osborn, D.L.; Choi, H.; Mordaunt, D.H.; Bise, R.T.; Neumark, D.M.; Rohlfing, C.M., Fast beam photodissociation spectroscopy and dynamics of the vinoxy radical, J. Chem. Phys., 1997, 106, 8, 3049, https://doi.org/10.1063/1.473419 . [all data]

Jacox, 1982
Jacox, M.E., The reaction of F atoms with acetaldehyde and ethylene oxide. Vibrational spectra of the CH3CO and CH2CHO free radicals trapped in solid argon, Chem. Phys., 1982, 69, 3, 407, https://doi.org/10.1016/0301-0104(82)88079-8 . [all data]

Notes

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