DCOOD+

Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 45610 ± 40 gas Leach, Schwell, et al., 2003
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' CO stretch 1749 ± 20 T gas PE Leach, Schwell, et al., 2003
CO stretch 1189 ± 20 gas PE Watanabe, Yokoyama, et al., 1973
Leach, Schwell, et al., 2003
962 ± 20 gas PE Leach, Schwell, et al., 2003
COD bend ? 827 ± 20 gas PE Watanabe, Yokoyama, et al., 1973
Leach, Schwell, et al., 2003
508 ± 20 gas PE Leach, Schwell, et al., 2003

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 45090 ± 20 gas Leach, Schwell, et al., 2003

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 32800 T gas Leach, Schwell, et al., 2003

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 28280 ± 100 gas Leach, Schwell, et al., 2003

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 8430 ± 25 gas Schwell, Leach, et al., 2001
Leach, Schwell, et al., 2003
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' CO stretch 2273 ± 20 T gas PE Watanabe, Yokoyama, et al., 1973
Schwell, Leach, et al., 2001
Leach, Schwell, et al., 2003
1085 ± 20 gas PE Watanabe, Yokoyama, et al., 1973
Schwell, Leach, et al., 2001
Leach, Schwell, et al., 2003
521 ± 20 gas PE Schwell, Leach, et al., 2001
Leach, Schwell, et al., 2003

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 OD stretch 2521.6 Ne IR Forney, Jacox, et al., 2003
3 CO stretch 1472 ± 20 gas PE Watanabe, Yokoyama, et al., 1973
Schwell, Leach, et al., 2001
Leach, Schwell, et al., 2003
3 CO stretch 1486.7 Ne IR Forney, Jacox, et al., 2003
4 1250 ± 20 T gas PE Leach, Schwell, et al., 2003
5 965 ± 20 gas PE Watanabe, Yokoyama, et al., 1973
Schwell, Leach, et al., 2001
Leach, Schwell, et al., 2003
6 855.3 Ne IR Forney, Jacox, et al., 2003
7 447 ± 20 gas PE Schwell, Leach, et al., 2001
Leach, Schwell, et al., 2003
a 9 530.9 Ne IR Forney, Jacox, et al., 2003

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Leach, Schwell, et al., 2003
Leach, S.; Schwell, M.; Talbi, D.; Berthier, G.; Hottmann, K.; Jochims, J.-W.; Baumgartel, H., He I photoelectron spectroscopy of four isotopologues of formic acid: HCOOH, HCOOD, DCOOH and DCOOD, Chem. Phys., 2003, 286, 1, 15, https://doi.org/10.1016/S0301-0104(02)00917-5 . [all data]

Watanabe, Yokoyama, et al., 1973
Watanabe, I.; Yokoyama, Y.; Ikeda, S., Vibrational structures in the photoelectron spectrum of formic acid, Chem. Phys. Lett., 1973, 19, 406. [all data]

Schwell, Leach, et al., 2001
Schwell, M.; Leach, S.; Hottmann, K.; Jochims, H.-W.; Baumgartel, H., He I photoelectron spectroscopy of formic acid isotopomers HCOOH and DCOOD, Chem. Phys., 2001, 272, 1, 77, https://doi.org/10.1016/S0301-0104(01)00443-8 . [all data]

Forney, Jacox, et al., 2003
Forney, D.; Jacox, M.E.; Thompson, W.E., Infrared spectra of trans-HOCO, HCOOH[sup +], and HCO[sub 2][sup -] trapped in solid neon, J. Chem. Phys., 2003, 119, 20, 10814, https://doi.org/10.1063/1.1621382 . [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References