D2CCN-

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   Dip
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 12360.434 gas Lykke, Neumark, et al., 1987

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 5 D2CC deform. 289.13 gas PD PE Marks, Wetzel, et al., 1986
Moran, Ellis, et al., 1987
Lykke, Neumark, et al., 1987

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lykke, Neumark, et al., 1987
Lykke, K.R.; Neumark, D.M.; Andersen, T.; Trapa, V.J.; Lineberger, W.C., Autodetachment spectroscopy and dynamics of CH2CN- and CD2CN-, J. Chem. Phys., 1987, 87, 12, 6842, https://doi.org/10.1063/1.453379 . [all data]

Marks, Wetzel, et al., 1986
Marks, J.; Wetzel, D.M.; Comita, P.B.; Brauman, J.I., A dipole supported state in cyanomethyl anion, the conjugate base of acetonitrile. Rotational band assignments in the electron photodetachment spectrum of -CH2CN, J. Chem. Phys., 1986, 84, 5284. [all data]

Moran, Ellis, et al., 1987
Moran, S.; Ellis, H.B., Jr.; DeFrees, D.J.; McLean, A.D.; Ellison, G.B., Carbanion spectroscopy: CH2CN-, J. Am. Chem. Soc., 1987, 109, 5996. [all data]

Notes

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