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CD3S


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 28089 gas Bise, Choi, et al., 1999

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 26574 gas A-X 339 378 Suzuki, Inoue, et al., 1984
Bise, Choi, et al., 1999


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 Umbrella 837 ± 1 gas LF Suzuki, Inoue, et al., 1984
3 CS stretch 395 ± 1 gas LF Suzuki, Inoue, et al., 1984
Bise, Choi, et al., 1999

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 Umbrella 1100 ± 50 gas PD Janousek and Brauman, 1980
3 CS stretch 667 ± 1 gas PD LF Janousek and Brauman, 1980
Suzuki, Inoue, et al., 1984
e 5 DCS deform. 780 gas PD Janousek and Brauman, 1980

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bise, Choi, et al., 1999
Bise, R.T.; Choi, H.; Pedersen, H.B.; Mordaunt, D.H.; Neumark, D.M., Photodissociation spectroscopy and dynamics of the methylthio radical (CH[sub 3]S), J. Chem. Phys., 1999, 110, 2, 805, https://doi.org/10.1063/1.478048 . [all data]

Suzuki, Inoue, et al., 1984
Suzuki, M.; Inoue, G.; Akimoto, H., Laser induced fluorescence of CH3S and CD3S radicals, J. Chem. Phys., 1984, 81, 12, 5405, https://doi.org/10.1063/1.447685 . [all data]

Janousek and Brauman, 1980
Janousek, B.K.; Brauman, J.I., Electron photodetachment of thiomethoxyl and deuterothiomethoxyl anions: Electron affinities, vibrational frequencies, and spin-orbit splitting in CH3S- and CD3S-, J. Chem. Phys., 1980, 72, 694. [all data]


Notes

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