CD2OD

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   3pz
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 40913 gas 3pz-X 216 244 Dulcey and Hudgens, 1986
Pagsberg, Munk, et al., 1989
Johnson and Hudgens, 1996

State:   3px
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 35124 gas 3px-X Pagsberg, Munk, et al., 1989

State:   3p

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 4 CO stretch 1565 gas MPI AB Dulcey and Hudgens, 1986
Pagsberg, Munk, et al., 1989
Johnson and Hudgens, 1996
5 CD2 scissors 1109 gas MPI AB Dulcey and Hudgens, 1986
Pagsberg, Munk, et al., 1989
Johnson and Hudgens, 1996
a 8 D2CO OPLA 952 ± 23 gas MPI Johnson and Hudgens, 1996
9 Torsion 723 ± 23 gas MPI Johnson and Hudgens, 1996

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 OD stretch 2694 w m Ar IR Jacox, 1981
1 OD stretch 2682 m N2 IR Jacox and Milligan, 1973
4 CO stretch 1221 ± 4 gas MPI Johnson and Hudgens, 1996
4 CO stretch 1223 m Ar IR Jacox, 1981
4 CO stretch 1222 m N2 IR Jacox and Milligan, 1973
5 CD2 scissors 1020 ± 5 gas MPI Johnson and Hudgens, 1996
5 CD2 scissors 1041 m Ar IR Jacox, 1981
7 765 w m Ar IR Jacox, 1981
a 8 Torsion 329 ± 23 gas MPI Johnson and Hudgens, 1996
9 D2CO OPLA 177 ± 23 gas MPI Johnson and Hudgens, 1996

Notes

wWeak
mMedium
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dulcey and Hudgens, 1986
Dulcey, C.S.; Hudgens, J.W., Multiphoton ionization spectroscopy and vibrational analysis of a 3p Rydberg state of the hydroxymethyl radical, J. Chem. Phys., 1986, 84, 10, 5262, https://doi.org/10.1063/1.449935 . [all data]

Pagsberg, Munk, et al., 1989
Pagsberg, P.; Munk, J.; Anastasi, C.; Simpson, V., UV spectrum of CD2OD and its reactions with O2, NO and NO2, Chem. Phys. Lett., 1989, 157, 3, 271, https://doi.org/10.1016/0009-2614(89)87246-X . [all data]

Johnson and Hudgens, 1996
Johnson, R.D., III; Hudgens, J.W., Structural and thermochemical properties of hydroxymethyl (CH2OH) radicals and cations derived from observations of B 2A'(3p)←X 2A" electronic spectra and from ab initio calculations, J. Phys. Chem., 1996, 100, 19874. [all data]

Jacox, 1981
Jacox, M.E., The reaction of excited argon atoms and of F atoms with Methanol. Vibrational spectrum of CH2OH isolated in solid argon, Chem. Phys., 1981, 59, 1-2, 213, https://doi.org/10.1016/0301-0104(81)80101-2 . [all data]

Jacox and Milligan, 1973
Jacox, M.E.; Milligan, D.E., Matrix isolation study of the vacuum-ultraviolet photolysis of methanol, J. Mol. Spectrosc., 1973, 47, 1, 148, https://doi.org/10.1016/0022-2852(73)90084-2 . [all data]

Notes

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