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DCOCl


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 32775.3 gas A-X 283 313 Judge and Moule, 1985


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 2 CO stretch 1092.0 gas AB Judge and Moule, 1985
4 CCl stretch 633.4 gas AB Judge and Moule, 1985
5 ClCO deform. 303.1 gas AB Judge and Moule, 1985
a 6 Umbrella (OPLA) 566.5 gas AB Judge and Moule, 1985

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 CD stretch 2204.3 gas IR Davis and Gerry, 1983
Joo, Laboy, et al., 1995
2 CO stretch 1749.1 gas IR Davis and Gerry, 1983
Joo, Laboy, et al., 1995
3 CD bend 986.11 gas IR Davis and Gerry, 1983
Joo, Laboy, et al., 1995
4 CCl stretch 700.77 gas IR Davis and Gerry, 1983
Joo, Laboy, et al., 1995
Joo, Clouthier, et al., 1995
5 CCl bend 455.78 gas IR Joo, Laboy, et al., 1995
a 6 OPLA 781.50 gas IR Joo, Laboy, et al., 1995
Joo, Clouthier, et al., 1995

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Judge and Moule, 1985
Judge, R.H.; Moule, D.C., The electronic transition in formyl chloride, CHClO, J. Mol. Spectrosc., 1985, 113, 2, 302, https://doi.org/10.1016/0022-2852(85)90269-3 . [all data]

Davis and Gerry, 1983
Davis, R.W.; Gerry, M.C.L., The microwave spectrum, harmonic force field, and structure of formyl chloride, J. Mol. Spectrosc., 1983, 97, 1, 117, https://doi.org/10.1016/0022-2852(83)90340-5 . [all data]

Joo, Laboy, et al., 1995
Joo, D.-L.; Laboy, J.; Kolomeisky, A.; Zhuo, Q.; Clouthier, D.J.; Chan, C.P.; Merer, A.J.; Judge, R.H., A High-Resolution Fourier Transform Infrared Study of the «nu»3, «nu»4, and «nu»5 Bands of Deuterated Formyl Chloride (DCOCl), J. Mol. Spectrosc., 1995, 170, 2, 346, https://doi.org/10.1006/jmsp.1995.1076 . [all data]

Joo, Clouthier, et al., 1995
Joo, D.-L.; Clouthier, D.J.; Merer, A.J., A High-Resolution Fourier Transform Infrared Study of the Out-of-Plane Bending Fundamentals of HCOCl and DCOCl, J. Mol. Spectrosc., 1995, 174, 2, 353, https://doi.org/10.1006/jmsp.1995.0007 . [all data]


Notes

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