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D2CS


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 47325.563 ± 0.004 gas C-X 211 212 Judge, Drury-Lessard, et al., 1978
Drury and Moule, 1982


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CD stretch 1783 gas AB Judge, Drury-Lessard, et al., 1978
Drury and Moule, 1982
2 CD2 scissors 746 gas AB Drury and Moule, 1982

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 45200 T gas B-X 185 215 Drury, Lai, et al., 1982


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 3 CS stretch 467 gas AB Drury, Lai, et al., 1982
b1 4 OPLA 263 H gas AB Drury, Lai, et al., 1982

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 16483.502 ± 0.008 gas A-X 440 610 Judge and King, 1975
Judge and King, 1979
Judge and King, 1979, 2


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CD stretch 2139 ± 2 gas AB Judge and King, 1979
2 CD2 scissors 1013 ± 2 gas AB Judge and King, 1979
3 CS stretch 771.3 ± 0.5 gas AB Judge and King, 1975
Judge and King, 1979
b1 4 OPLA 275.33 gas AB Judge and King, 1979
b2 5 CD stretch 2324.85 gas AB Judge and King, 1979
6 CD2 rock 599 ± 2 gas AB Judge and King, 1979

State:   a


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 14613.54 gas a-X 610 815 Judge and King, 1975
Judge, Moule, et al., 1980
Glinski, Getty, et al., 1985
Glinski, Taylor, et al., 1991


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 CD2 scissors 1012 gas AB CL Judge, Moule, et al., 1980
Glinski, Taylor, et al., 1991
3 CS stretch 798 gas AB CL Judge and King, 1975
Judge, Moule, et al., 1980
Glinski, Taylor, et al., 1991
b1 4 OPLA 219.4 ± 5.0 gas AB CL Jensen and Bunker, 1982
Glinski, Getty, et al., 1985
Glinski, Taylor, et al., 1991
b2 6 CD2 rock 572.6 ± 5.0 gas CL Glinski, Taylor, et al., 1991

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CD stretch 2158.5 gas IR Turner, Halonen, et al., 1981
1 CD stretch 2155 m Ar IR Torres, Safarik, et al., 1982
2 CD2 scissors 1171.8 gas IR Turner, Halonen, et al., 1981
2 CD2 scissors 1167 m N2 IR Torres, Safarik, et al., 1982
3 CS stretch 936.13 gas IR LS Turner, Halonen, et al., 1981
Duxbury, Kato, et al., 1981
3 CS stretch 941 w Ar IR Jacox and Milligan, 1975
Torres, Safarik, et al., 1982
3 CS stretch 939 w m N2 IR Jacox and Milligan, 1975
b1 4 OPLA 781.2 gas IR Turner, Halonen, et al., 1981
4 OPLA 783 m Ar IR Jacox and Milligan, 1975
Torres, Safarik, et al., 1982
4 OPLA 784 s N2 IR Jacox and Milligan, 1975
b2 6 CD2 rock 757.4 gas IR Turner, Halonen, et al., 1981

Notes

wWeak
mMedium
sStrong
H(1/2)(2nu)
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Judge, Drury-Lessard, et al., 1978
Judge, R.H.; Drury-Lessard, C.R.; Moule, D.C., The far ultraviolet spectrum of thioformaldehyde, Chem. Phys. Lett., 1978, 53, 1, 82, https://doi.org/10.1016/0009-2614(78)80395-9 . [all data]

Drury and Moule, 1982
Drury, C.R.; Moule, D.C., The ultraviolet absorption spectrum of thioformaldehyde, J. Mol. Spectrosc., 1982, 92, 2, 469, https://doi.org/10.1016/0022-2852(82)90116-3 . [all data]

Drury, Lai, et al., 1982
Drury, C.R.; Lai, J.Y.K.; Moule, D.C., The B1A2 <-- X1A1 absorption spectrum of thioformaldehyde, Chem. Phys. Lett., 1982, 87, 6, 520, https://doi.org/10.1016/0009-2614(82)83169-2 . [all data]

Judge and King, 1975
Judge, R.H.; King, G.W., The Electronic Absorption Spectrum of Thioformaldehyde, Can. J. Phys., 1975, 53, 19, 1927, https://doi.org/10.1139/p75-241 . [all data]

Judge and King, 1979
Judge, R.H.; King, G.W., Thioformaldehyde, J. Mol. Spectrosc., 1979, 74, 2, 175, https://doi.org/10.1016/0022-2852(79)90048-1 . [all data]

Judge and King, 1979, 2
Judge, R.H.; King, G.W., Thioformaldehyde, J. Mol. Spectrosc., 1979, 78, 1, 51, https://doi.org/10.1016/0022-2852(79)90035-3 . [all data]

Judge, Moule, et al., 1980
Judge, R.H.; Moule, D.C.; King, G.W., The absorption spectrum of thioformaldehyde, J. Mol. Spectrosc., 1980, 81, 1, 37, https://doi.org/10.1016/0022-2852(80)90328-8 . [all data]

Glinski, Getty, et al., 1985
Glinski, R.J.; Getty, J.N.; Birks, J.W., Phosphorescence spectra of thioformaldehyde and thioformaldehyde-d2 by chemiluminescence: Identification of the 411 band, Chem. Phys. Lett., 1985, 117, 4, 359, https://doi.org/10.1016/0009-2614(85)85244-1 . [all data]

Glinski, Taylor, et al., 1991
Glinski, R.J.; Taylor, C.D.; Martin, H.R., Chemiluminescence spectra of thioformaldehyde and selenoformaldehyde, J. Phys. Chem., 1991, 95, 16, 6159, https://doi.org/10.1021/j100169a021 . [all data]

Jensen and Bunker, 1982
Jensen, P.; Bunker, P.R., The geometry and the out-of-plane bending potential function of thioformaldehyde in the and electronic states, J. Mol. Spectrosc., 1982, 95, 1, 92, https://doi.org/10.1016/0022-2852(82)90241-7 . [all data]

Turner, Halonen, et al., 1981
Turner, P.H.; Halonen, L.; Mills, I.M., Fourier transform infrared spectra of H2CS and D2CS, J. Mol. Spectrosc., 1981, 88, 2, 402, https://doi.org/10.1016/0022-2852(81)90190-9 . [all data]

Torres, Safarik, et al., 1982
Torres, M.; Safarik, I.; Clement, A.; Strausz, O.P., The generation and vibrational spectrum of matrix isolated thioformaldehyde and dideuterothioformaldehyde, Can. J. Chem., 1982, 60, 10, 1187, https://doi.org/10.1139/v82-176 . [all data]

Duxbury, Kato, et al., 1981
Duxbury, G.; Kato, H.; Le Lerre, M.L., Laser Stark and interferometric studies of thioformaldehyde and methyleneimine, Discuss. Faraday Soc., 1981, 71, 97, https://doi.org/10.1039/dc9817100097 . [all data]

Jacox and Milligan, 1975
Jacox, M.E.; Milligan, D.E., Matrix isolation study of the infrared spectrum of thioformaldehyde, J. Mol. Spectrosc., 1975, 58, 1, 142, https://doi.org/10.1016/0022-2852(75)90162-9 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References