SiD3

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   Π
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 62002 gas Π-X Johnson III, Tsai, et al., 1989
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a2 2 OPLA 615 ± 3 gas MPI Johnson III, Tsai, et al., 1989

State:   N
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 61005 gas N-X Johnson III, Tsai, et al., 1989
Johnson and Hudgens, 1991
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a2 2 OPLA 619 ± 7 gas MPI Johnson III, Tsai, et al., 1989

State:   M
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 60267 gas M-X Johnson III, Tsai, et al., 1989
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a2 2 OPLA 615 ± 4 gas MPI Johnson III, Tsai, et al., 1989

State:   K
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 58417 gas K-X Johnson III, Tsai, et al., 1989
Johnson and Hudgens, 1991
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a2 2 OPLA 602 ± 10 gas MPI Johnson and Hudgens, 1991

State:   J'
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 57840 ± 30 gas J'-X Johnson and Hudgens, 1991
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a2 2 OPLA 603 ± 20 gas MPI Johnson and Hudgens, 1991

State:   J
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 56874 gas J-X Johnson III, Tsai, et al., 1989
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a2 2 OPLA 608 ± 3 gas MPI Johnson III, Tsai, et al., 1989

State:   I'
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 56205 ± 30 gas I'-X Johnson and Hudgens, 1991
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a2 2 OPLA 600 ± 17 gas MPI Johnson and Hudgens, 1991

State:   H
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 50000 T gas H-X Johnson III, Tsai, et al., 1989
Johnson and Hudgens, 1991
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a2 2 OPLA 602 ± 5 gas MPI Johnson III, Tsai, et al., 1989

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 49685 ± 30 gas D-X Johnson and Hudgens, 1991
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a2 2 OPLA 600 ± 28 gas MPI Johnson and Hudgens, 1991

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 48391 gas E-X Johnson III, Tsai, et al., 1989
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1' 1 SiD3 stretch 1576 ± 3 gas MPI Johnson III, Tsai, et al., 1989
a2 2 OPLA 589 ± 3 gas MPI Johnson III, Tsai, et al., 1989
e' 4 Deformation 635 ± 6 H gas MPI Johnson III, Tsai, et al., 1989

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 2 Umbrella 545 I gas MPI Johnson III, Tsai, et al., 1989
2 Umbrella 542 I gas MPI Johnson III, Tsai, et al., 1989
2 Umbrella 552.3 Ne IR Andrews and Wang, 2002
2 Umbrella 546.2 Ne IR Andrews and Wang, 2002
2 Umbrella 547.2 Ar IR Li, Graham, et al., 2001
Andrews and Wang, 2002
2 Umbrella 545.4 Ar IR Li, Graham, et al., 2001
Andrews and Wang, 2002
2 Umbrella 548.9 Kr IR Legay-Sommaire and Legay, 1998
2 Umbrella 547.2 Kr IR Legay-Sommaire and Legay, 1998
2 Umbrella 545.7 D2 IR Li, Graham, et al., 2001
Andrews and Wang, 2002
e 4 Deformation 668.7 D2 IR Andrews and Wang, 2002

Notes

H(1/2)(2ν)
IComponent of an inversion doublet
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Johnson III, Tsai, et al., 1989
Johnson III, R.D.; Tsai, B.P.; Hudgens, J.W., Multiphoton ionization of SiH3 and SID3 radicals: Electronic spectra, vibrational analyses of the ground and Rydberg states, and ionization potentials, J. Chem. Phys., 1989, 91, 3340. [all data]

Johnson and Hudgens, 1991
Johnson, R.D., III; Hudgens, J.W., Multiphoton ionization of SiH3 and SiD3 radicals. II. Three-photon resonance-enhanced spectra observed between 450 and 610 nm, J. Chem. Phys., 1991, 94, 8, 5331, https://doi.org/10.1063/1.460518 . [all data]

Andrews and Wang, 2002
Andrews, L.; Wang, X., Infrared Spectra of the Novel Si, J. Phys. Chem. A, 2002, 106, 34, 7696, https://doi.org/10.1021/jp0204814 . [all data]

Li, Graham, et al., 2001
Li, L.; Graham, J.T.; Weltner, W., Jr., Infrared Spectra of Silane in Solid Argon and Hydrogen, J. Phys. Chem. A, 2001, 105, 49, 11018, https://doi.org/10.1021/jp013003m . [all data]

Legay-Sommaire and Legay, 1998
Legay-Sommaire, N.; Legay, F., Photochemical Insertion Reaction of Hg in SiH, J. Phys. Chem. A, 1998, 102, 45, 8759, https://doi.org/10.1021/jp9821533 . [all data]

Notes

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