GeD2

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 16324.34 gas A-X 500 850 Saito and Obi, 1993
Saito and Obi, 1994
Smith, Clouthier, et al., 2000
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 1304 gas LF Smith, Clouthier, et al., 2000
2 Bend 561 gas LF Saito and Obi, 1993
Saito and Obi, 1994
Smith, Clouthier, et al., 2000

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 1335 gas LF Smith, Clouthier, et al., 2000
1 Sym. stretch 1342.6 Ne IR Wang, Andrews, et al., 2002
1 Sym. stretch 1337.3 Ne IR Wang, Andrews, et al., 2002
1 Sym. stretch 1325.4 Ar IR Smith and Guillory, 1972
Wang, Andrews, et al., 2002
1 Sym. stretch 1338.4 D2 IR Wang, Andrews, et al., 2002
1 Sym. stretch 1332.7 D2 IR Wang, Andrews, et al., 2002
2 Bend 657 gas LF Saito and Obi, 1993
Smith, Clouthier, et al., 2000
2 Bend 660.2 Ne IR Wang, Andrews, et al., 2002
2 Bend 654.4 Ar IR Smith and Guillory, 1972
Wang, Andrews, et al., 2002
2 Bend 646.5 D2 IR Wang, Andrews, et al., 2002
b2 3 Asym. stretch 1342.6 Ne IR Wang, Andrews, et al., 2002
3 Asym. stretch 1337.3 Ne IR Wang, Andrews, et al., 2002
3 Asym. stretch 1325.4 Ar IR Smith and Guillory, 1972
Wang, Andrews, et al., 2002
3 Asym. stretch 1338.4 D2 IR Wang, Andrews, et al., 2002
3 Asym. stretch 1332.7 D2 IR Wang, Andrews, et al., 2002

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Saito and Obi, 1993
Saito, K.; Obi, K., The first observation of the à 1B1-X 1A1 transition of GeH2 and GeD2 radicals, Chem. Phys. Lett., 1993, 215, 1-3, 193, https://doi.org/10.1016/0009-2614(93)89287-R . [all data]

Saito and Obi, 1994
Saito, K.; Obi, K., The excited state dynamics of the Ã1B1 state of GeH2 and GeD2 radicals, Chem. Phys., 1994, 187, 3, 381, https://doi.org/10.1016/0301-0104(94)89020-X . [all data]

Smith, Clouthier, et al., 2000
Smith, T.C.; Clouthier, D.J.; Sha, W.; Adam, A.G., Laser optogalvanic and jet spectroscopy of germylene (GeH[sub 2]): New spectroscopic data for an important semiconductor growth intermediate, J. Chem. Phys., 2000, 113, 21, 9567, https://doi.org/10.1063/1.1319936 . [all data]

Wang, Andrews, et al., 2002
Wang, X.; Andrews, L.; Kushto, G.P., Infrared Spectra of the Novel Ge, J. Phys. Chem. A, 2002, 106, 24, 5809, https://doi.org/10.1021/jp020219v . [all data]

Smith and Guillory, 1972
Smith, G.R.; Guillory, W.A., Products of the Vacuum-Ultraviolet Photolysis of Germane Isolated in an Argon Matrix, J. Chem. Phys., 1972, 56, 4, 1423, https://doi.org/10.1063/1.1677383 . [all data]

Notes

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