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DSO


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 14371 gas A-X 520 960 Schurath, Weber, et al., 1977
Takehisa and Ohashi, 1988


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 2 Bend 575 ± 10 gas LF Ohashi, Saito, et al., 1988
3 SO stretch 702 ± 10 gas CL Schurath, Weber, et al., 1977

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 SD stretch 1696 ± 5 gas LF Yoshikawa, Watanabe, et al., 2009
2 Bend 777 ± 5 gas CL LF Schurath, Weber, et al., 1977
Yoshikawa, Watanabe, et al., 2009
3 SO stretch 1049 ± 5 gas CL LF Schurath, Weber, et al., 1977
Yoshikawa, Watanabe, et al., 2009

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schurath, Weber, et al., 1977
Schurath, U.; Weber, M.; Becker, K.H., Electronic spectrum and structure of the HSO radical, J. Chem. Phys., 1977, 67, 1, 110, https://doi.org/10.1063/1.434553 . [all data]

Takehisa and Ohashi, 1988
Takehisa, Y.; Ohashi, N., Dye laser excitation spectroscopy of the DSO radical in the A2A´(022) <-- X2A´´(000) band, J. Mol. Spectrosc., 1988, 130, 1, 221, https://doi.org/10.1016/0022-2852(88)90295-0 . [all data]

Ohashi, Saito, et al., 1988
Ohashi, N.; Saito, S.; Suzuki, T.; Hirota, E., Dye laser excitation spectroscopy of two new bands of the DSO radical in 6100-Å region, J. Mol. Spectrosc., 1988, 127, 2, 481, https://doi.org/10.1016/0022-2852(88)90136-1 . [all data]

Yoshikawa, Watanabe, et al., 2009
Yoshikawa, T.; Watanabe, A.; Sumiyoshi, Y.; Endo, Y., Laser spectroscopy of the 2A´-2A´´ system for the HSO radical, J. Mol. Spectrosc., 2009, 254, 2, 119, https://doi.org/10.1016/j.jms.2009.01.018 . [all data]


Notes

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