DNF

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 20169.10 gas A-X 400 500 Chen and Dagdigian, 1992
Chen and Dagdigian, 1993
Chen and Dagdigian, 1993, 2
To = 20220 Ar A-X 413 495 Jacox and Milligan, 1967
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 2 Bend 837.4 ± 0.8 gas LF Chen and Dagdigian, 1992
2 Bend 798 T Ar AB Jacox and Milligan, 1967
3 NF stretch 1124 gas LF Chen and Dagdigian, 1992

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 ND stretch 2339 ± 4 gas LF Chen and Dagdigian, 1993
2 Bend 1075 ± 3 gas LF Chen and Dagdigian, 1993
2 Bend 1069 Ar IR Jacox and Milligan, 1967
3 NF stretch 1007 ± 7 gas LF Chen and Dagdigian, 1993
3 NF stretch 1000 s Ar IR Jacox and Milligan, 1967

Notes

sStrong
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chen and Dagdigian, 1992
Chen, J.; Dagdigian, P.J., Spectroscopy and excited state dynamics of the HNF (DNF) molecule, J. Chem. Phys., 1992, 96, 10, 7333, https://doi.org/10.1063/1.462436 . [all data]

Chen and Dagdigian, 1993
Chen, J.; Dagdigian, P.J., Spectrally resolved fluorescence in the HNF (DNF) Ã2A´ - X2 A´´ band system, Chem. Phys. Lett., 1993, 213, 5-6, 586, https://doi.org/10.1016/0009-2614(93)89165-E . [all data]

Chen and Dagdigian, 1993, 2
Chen, J.; Dagdigian, P.J., The DNF Ã2A´-X2A´´ Band System: Rotational Analysis of the Origin Band and Partial Analysis of Several Higher Bands, J. Mol. Spectrosc., 1993, 162, 1, 152, https://doi.org/10.1006/jmsp.1993.1275 . [all data]

Jacox and Milligan, 1967
Jacox, M.E.; Milligan, D.E., Production and Reaction of Atomic Fluorine in Solids. Vibrational and Electronic Spectra of the Free Radical HNF, J. Chem. Phys., 1967, 46, 1, 184, https://doi.org/10.1063/1.1840369 . [all data]

Notes

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