DGeCl


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 21614.48 gas A-X 441 462 Harper and Clouthier, 1998


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 GeD stretch 979.6 ± 0.2 gas LF Harper and Clouthier, 1998
2 Bend 321.7 ± 0.2 gas LF Harper and Clouthier, 1998
3 GeCl stretch 398.9 ± 0.2 gas LF Harper and Clouthier, 1998

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 GeD stretch 1320 ± 2 gas LF Tackett, Clouthier, et al., 2006
1 GeD stretch 1343 w Ar IR Isabel and Guillory, 1971
2 Bend 521 ± 2 gas LF Tackett, Clouthier, et al., 2006
3 GeCl stretch 398 ± 2 gas LF Tackett, Clouthier, et al., 2006

Notes

wWeak
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Harper and Clouthier, 1998
Harper, W.W.; Clouthier, D.J., The electronic spectra of jet-cooled HGeCl and HGeBr, J. Chem. Phys., 1998, 108, 2, 416, https://doi.org/10.1063/1.475403 . [all data]

Tackett, Clouthier, et al., 2006
Tackett, B.S.; Clouthier, D.J.; Pacheco, K.L.; Schick, G.A., The ground state energy levels and molecular structure of jet-cooled HGeCl and DGeCl from single vibronic level emission spectroscopy, J. Chem. Phys., 2006, 124, 12, 124320, https://doi.org/10.1063/1.2181142 . [all data]

Isabel and Guillory, 1971
Isabel, R.J.; Guillory, W.A., Vacuum-Ultraviolet Photolysis of GeH3Cl; the Infrared Spectrum of Matrix-Isolated GeH2Cl, J. Chem. Phys., 1971, 55, 3, 1197, https://doi.org/10.1063/1.1676205 . [all data]


Notes

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