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DCCl


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 12274 gas A-X 500 820 Merer and Travis, 1966
Lee, Liu, et al., 2002
Lin, Kobayashi, et al., 2002
Lin, Chen, et al., 2004
Tao, Mukarakate, et al., 2007


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 CD stretch 2229.6 gas LF Tao, Mukarakate, et al., 2007
2 Bend 657.2 gas AB Merer and Travis, 1966

State:   a


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 2163.28 ± 0.05 gas Lin, Chen, et al., 2004
Tao, Mukarakate, et al., 2006
Tao, Mukarakate, et al., 2008
Tao, Mukarakate, et al., 2008, 2


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 CD stretch 2283 T gas LF Tao, Mukarakate, et al., 2007
2 Bend 708 ± 2 H gas LF SEP Tao, Mukarakate, et al., 2007
Tao, Mukarakate, et al., 2008, 2
3 CCl stretch 883 ± 4 gas LF Tao, Mukarakate, et al., 2007

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 CD stretch 2078.2 gas LF SEP Lee, Liu, et al., 2002
Lin, Chen, et al., 2004
Tao, Mukarakate, et al., 2007
Tao, Mukarakate, et al., 2008, 2
2 Bend 889.7 gas LF SEP Lee, Liu, et al., 2002
Lin, Chen, et al., 2004
Tao, Mukarakate, et al., 2007
Tao, Mukarakate, et al., 2008, 2
3 CCl stretch 798.9 gas LF SEP Lee, Liu, et al., 2002
Lin, Chen, et al., 2004
Tao, Mukarakate, et al., 2007
Tao, Mukarakate, et al., 2008, 2
3 CCl stretch 805 s Ar IR Jacox and Milligan, 1967

Notes

sStrong
H(1/2)(2nu)
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Merer and Travis, 1966
Merer, A.J.; Travis, D.N., ABSORPTION SPECTRA OF HCCl AND DCCl, Can. J. Phys., 1966, 44, 3, 525, https://doi.org/10.1139/p66-047 . [all data]

Lee, Liu, et al., 2002
Lee, C.-L.; Liu, M.-L.; Chang, B.-C., Experimental study of the DCCl X[sup 1]A[sup ´] state vibrational structure by dispersed fluorescence spectroscopy, J. Chem. Phys., 2002, 117, 7, 3263, https://doi.org/10.1063/1.1485768 . [all data]

Lin, Kobayashi, et al., 2002
Lin, A.; Kobayashi, K.; Yu, H.-G.; Hall, G.E.; Muckerman, J.T.; Sears, T.J.; Merer, A.J., Axis-Switching and Coriolis Coupling in the Ã(010)--X(000) Transitions of DCCl and HCCl, J. Mol. Spectrosc., 2002, 214, 2, 216, https://doi.org/10.1006/jmsp.2002.8594 . [all data]

Lin, Chen, et al., 2004
Lin, C.-S.; Chen, Y.-E.; Chang, B.-C., New electronic spectra of the HCCl and DCCl A-X vibronic bands, J. Chem. Phys., 2004, 121, 9, 4164, https://doi.org/10.1063/1.1779572 . [all data]

Tao, Mukarakate, et al., 2007
Tao, C.; Mukarakate, C.; Reid, S.A., Electronic spectroscopy of the system of CDCl, J. Mol. Spectrosc., 2007, 241, 2, 143, https://doi.org/10.1016/j.jms.2006.12.001 . [all data]

Tao, Mukarakate, et al., 2006
Tao, C.; Mukarakate, C.; Reid, S.A., Fluorescence excitation and single vibronic level emission spectroscopy of the A [sup 1]A[sup ´´]<--X [sup 1]A[sup ´] system of CHCl, J. Chem. Phys., 2006, 124, 22, 224314, https://doi.org/10.1063/1.2204916 . [all data]

Tao, Mukarakate, et al., 2008
Tao, C.; Mukarakate, C.; Judge, R.H.; Reid, S.A., High resolution probe of spin-orbit coupling and the singlet-triplet gap in chlorocarbene, J. Chem. Phys., 2008, 128, 17, 171101, https://doi.org/10.1063/1.2918727 . [all data]

Tao, Mukarakate, et al., 2008, 2
Tao, C.; Mukarakate, C.; Terranova, Z.; Ebben, C.; Judge, R.H.; Reid, S.A., High resolution study of spin-orbit mixing and the singlet-triplet gap in chlorocarbene: Stimulated emission pumping spectroscopy of CH[sup 35]Cl and CD[sup 35]Cl, J. Chem. Phys., 2008, 129, 10, 104309, https://doi.org/10.1063/1.2977686 . [all data]

Jacox and Milligan, 1967
Jacox, M.E.; Milligan, D.E., Matrix-Isolation Study of the Reaction of Carbon Atoms with HCl. The Infrared Spectrum of the Free Radical HCCl, J. Chem. Phys., 1967, 47, 5, 1626, https://doi.org/10.1063/1.1712143 . [all data]


Notes

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