DCCl
- Formula: CDCl
- Molecular weight: 49.478
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 12274 | gas | A-X | 500 | 820 | Merer and Travis, 1966 | ||
Lee, Liu, et al., 2002 | |||||||
Lin, Kobayashi, et al., 2002 | |||||||
Lin, Chen, et al., 2004 | |||||||
Tao, Mukarakate, et al., 2007 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a' | 1 | CD stretch | 2229.6 | gas | LF | Tao, Mukarakate, et al., 2007 | |
2 | Bend | 657.2 | gas | AB | Merer and Travis, 1966 | ||
State: a
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 2163.28 ± 0.05 | gas | Lin, Chen, et al., 2004 | |||||
Tao, Mukarakate, et al., 2006 | |||||||
Tao, Mukarakate, et al., 2008 | |||||||
Tao, Mukarakate, et al., 2008, 2 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a' | 1 | CD stretch | 2283 | T | gas | LF | Tao, Mukarakate, et al., 2007 |
2 | Bend | 708 ± 2 | H | gas | LF SEP | Tao, Mukarakate, et al., 2007 Tao, Mukarakate, et al., 2008, 2 | |
3 | CCl stretch | 883 ± 4 | gas | LF | Tao, Mukarakate, et al., 2007 | ||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a' | 1 | CD stretch | 2078.2 | gas | LF SEP | Lee, Liu, et al., 2002 Lin, Chen, et al., 2004 Tao, Mukarakate, et al., 2007 Tao, Mukarakate, et al., 2008, 2 | |
2 | Bend | 889.7 | gas | LF SEP | Lee, Liu, et al., 2002 Lin, Chen, et al., 2004 Tao, Mukarakate, et al., 2007 Tao, Mukarakate, et al., 2008, 2 | ||
3 | CCl stretch | 798.9 | gas | LF SEP | Lee, Liu, et al., 2002 Lin, Chen, et al., 2004 Tao, Mukarakate, et al., 2007 Tao, Mukarakate, et al., 2008, 2 | ||
3 | CCl stretch | 805 | s | Ar | IR | Jacox and Milligan, 1967 | |
Notes
s | Strong |
H | (1/2)(2ν) |
T | Tentative assignment or approximate value |
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Merer and Travis, 1966
Merer, A.J.; Travis, D.N.,
ABSORPTION SPECTRA OF HCCl AND DCCl,
Can. J. Phys., 1966, 44, 3, 525, https://doi.org/10.1139/p66-047
. [all data]
Lee, Liu, et al., 2002
Lee, C.-L.; Liu, M.-L.; Chang, B.-C.,
Experimental study of the DCCl X[sup 1]A[sup ´] state vibrational structure by dispersed fluorescence spectroscopy,
J. Chem. Phys., 2002, 117, 7, 3263, https://doi.org/10.1063/1.1485768
. [all data]
Lin, Kobayashi, et al., 2002
Lin, A.; Kobayashi, K.; Yu, H.-G.; Hall, G.E.; Muckerman, J.T.; Sears, T.J.; Merer, A.J.,
Axis-Switching and Coriolis Coupling in the Ã(010)--X(000) Transitions of DCCl and HCCl,
J. Mol. Spectrosc., 2002, 214, 2, 216, https://doi.org/10.1006/jmsp.2002.8594
. [all data]
Lin, Chen, et al., 2004
Lin, C.-S.; Chen, Y.-E.; Chang, B.-C.,
New electronic spectra of the HCCl and DCCl A-X vibronic bands,
J. Chem. Phys., 2004, 121, 9, 4164, https://doi.org/10.1063/1.1779572
. [all data]
Tao, Mukarakate, et al., 2007
Tao, C.; Mukarakate, C.; Reid, S.A.,
Electronic spectroscopy of the system of CDCl,
J. Mol. Spectrosc., 2007, 241, 2, 143, https://doi.org/10.1016/j.jms.2006.12.001
. [all data]
Tao, Mukarakate, et al., 2006
Tao, C.; Mukarakate, C.; Reid, S.A.,
Fluorescence excitation and single vibronic level emission spectroscopy of the A [sup 1]A[sup ´´]←X [sup 1]A[sup ´] system of CHCl,
J. Chem. Phys., 2006, 124, 22, 224314, https://doi.org/10.1063/1.2204916
. [all data]
Tao, Mukarakate, et al., 2008
Tao, C.; Mukarakate, C.; Judge, R.H.; Reid, S.A.,
High resolution probe of spin-orbit coupling and the singlet-triplet gap in chlorocarbene,
J. Chem. Phys., 2008, 128, 17, 171101, https://doi.org/10.1063/1.2918727
. [all data]
Tao, Mukarakate, et al., 2008, 2
Tao, C.; Mukarakate, C.; Terranova, Z.; Ebben, C.; Judge, R.H.; Reid, S.A.,
High resolution study of spin-orbit mixing and the singlet-triplet gap in chlorocarbene: Stimulated emission pumping spectroscopy of CH[sup 35]Cl and CD[sup 35]Cl,
J. Chem. Phys., 2008, 129, 10, 104309, https://doi.org/10.1063/1.2977686
. [all data]
Jacox and Milligan, 1967
Jacox, M.E.; Milligan, D.E.,
Matrix-Isolation Study of the Reaction of Carbon Atoms with HCl. The Infrared Spectrum of the Free Radical HCCl,
J. Chem. Phys., 1967, 47, 5, 1626, https://doi.org/10.1063/1.1712143
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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