CaOD

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 32628.3 gas Hailey, Jarman, et al., 1997
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend 267 gas DR Hailey, Jarman, et al., 1997

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 21907.128 gas C-X 440 470 Jarman and Bernath, 1992
Jakubek and Field, 1993
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend 235.38 gas LF Jarman and Bernath, 1992
Σ+ 3 CaO stretch 549 gas LF Jarman and Bernath, 1992

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 18013.894 ± 0.004 gas B-X Hailey, Jarman, et al., 1991

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 15995.016 gas Hilborn, Qingshi, et al., 1983
Coxon, Li, et al., 1991
Li and Coxon, 1994
Li and Coxon, 1996
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend 273.33 gas LF Li and Coxon, 1995
Σ+ 3 CaO stretch 623 ± 2 gas LF Hilborn, Qingshi, et al., 1983

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend 266.84 gas LF Coxon, Li, et al., 1992
Jarman and Bernath, 1992
Li and Coxon, 1995
Σ+ 3 CaO stretch 604.90 gas LF Hilborn, Qingshi, et al., 1983
Coxon, Li, et al., 1992

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hailey, Jarman, et al., 1997
Hailey, R.A.; Jarman, C.; Bernath, P.F., Optical--optical double resonance spectroscopy: The G [sup 2]Π state of CaOH and CaOD, J. Chem. Phys., 1997, 107, 2, 669, https://doi.org/10.1063/1.474428 . [all data]

Jarman and Bernath, 1992
Jarman, C.N.; Bernath, P.F., High resolution laser spectroscopy of the C 2Δ--X 2Σ+ transition of CaOH and CaOD: Vibronic coupling and the Renner--Teller effect, J. Chem. Phys., 1992, 97, 3, 1711, https://doi.org/10.1063/1.463158 . [all data]

Jakubek and Field, 1993
Jakubek, Z.J.; Field, R.W., Comment on: High resolution laser spectroscopy of the C 2Δ--X 2Σ+ transition of CaOH and CaOD: Vibronic coupling and the Renner--Teller effect, J. Chem. Phys., 1993, 98, 8, 6574, https://doi.org/10.1063/1.464801 . [all data]

Hailey, Jarman, et al., 1991
Hailey, R.A.; Jarman, C.N.; Fernando, W.T.M.L.; Bernath, P.F., The transition of CaOD, J. Mol. Spectrosc., 1991, 147, 1, 40, https://doi.org/10.1016/0022-2852(91)90166-8 . [all data]

Hilborn, Qingshi, et al., 1983
Hilborn, R.C.; Qingshi, Z.; Harris, D.O., Laser spectroscopy of the A-X transitions of CaOH and CaOD, J. Mol. Spectrosc., 1983, 97, 1, 73, https://doi.org/10.1016/0022-2852(83)90338-7 . [all data]

Coxon, Li, et al., 1991
Coxon, J.A.; Li, M.; Presunka, P.I., Laser fluorescence excitation spectroscopy of CaOH and CaOD: The A2Π-X2Σ+ (100)-(000) band system and the (100)-(020) Fermi resonance, J. Mol. Spectrosc., 1991, 150, 1, 33, https://doi.org/10.1016/0022-2852(91)90191-C . [all data]

Li and Coxon, 1994
Li, M.; Coxon, J.A., High-resolution spectroscopy of the (000)--(000) band of the CaOD radical, Can. J. Phys., 1994, 72, 11-12, 1200, https://doi.org/10.1139/p94-154 . [all data]

Li and Coxon, 1996
Li, M.; Coxon, J.A., Dye laser excitation studies of the A 2Π(100)/(020)--X 2Σ+(020)/(000) bands of CaOD: Analysis of the A 2Π(100)«tilde»(020) Fermi resonance, J. Chem. Phys., 1996, 104, 13, 4961, https://doi.org/10.1063/1.471762 . [all data]

Li and Coxon, 1995
Li, M.; Coxon, J.A., High-resolution analysis of the fundamental bending vibrations in the A 2Π and X 2Σ+ states of CaOH and CaOD: Deperturbation of Renner--Teller, spin--orbit and K-type resonance interactions, J. Chem. Phys., 1995, 102, 7, 2663, https://doi.org/10.1063/1.468643 . [all data]

Coxon, Li, et al., 1992
Coxon, J.A.; Li, M.; Presunka, P.I., Investigation of excited vibrational levels in the, Mol. Phys., 1992, 76, 6, 1463, https://doi.org/10.1080/00268979200102231 . [all data]

Notes

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