D2O+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 37430 ± 50 gas Karlsson, Mattson, et al., 1975
Dixon, Duxbury, et al., 1976
Reutt, Wang, et al., 1986
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 2282 gas PE Karlsson, Mattson, et al., 1975
Reutt, Wang, et al., 1986
2 Bend 1099 gas PE Reutt, Wang, et al., 1986

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
T = 10456 ± 30 gas A-X 490 820 Karlsson, Mattson, et al., 1975
Dixon, Duxbury, et al., 1976
Lew and Groleau, 1987
Gan, Yang, et al., 2004
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 2531 ± 8 gas PE Reutt, Wang, et al., 1986
2 Bend 640 ± 9 gas PE Reutt, Wang, et al., 1986

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 2344 ± 6 gas PE Karlsson, Mattson, et al., 1975
Dixon, Duxbury, et al., 1976
Reutt, Wang, et al., 1986
1 Sym. stretch 2326.7 Ne IR Forney, Jacox, et al., 1993
1 Sym. stretch 2209.4 Ar IR Zhou, Yang, et al., 2005
2 Bend 1044.29 gas EM DL Lew and Groleau, 1987
Duan, Zheng, et al., 2008
2 Bend 1040.5 Ne IR Forney, Jacox, et al., 1993
b2 3 Asym. stretch 2392.7 Ne IR Forney, Jacox, et al., 1993
3 Asym. stretch 2243.1 Ar IR Zhou, Yang, et al., 2005

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Karlsson, Mattson, et al., 1975
Karlsson, L.; Mattson, L.; Jadrny, R.; Albridge, R.G.; Pinchas, S.; Bergmark, T.; Siegbahn, K., Isotopic and vibronic coupling effects in the valence electron spectra of H216O, H218O, and D216O, J. Chem. Phys., 1975, 62, 4745. [all data]

Dixon, Duxbury, et al., 1976
Dixon, R.N.; Duxbury, G.; Rabalais, J.W.; Asbrink, L., Rovibronic structure in the photoelectron spectra of H2O, D2O and HDO, Mol. Phys., 1976, 31, 423. [all data]

Reutt, Wang, et al., 1986
Reutt, J.E.; Wang, L.S.; Lee, Y.T.; Shirley, D.A., Molecular beam photoelectron spectroscopy and femtosecond intramolecular dynamics of H2O+ and D2O+, J. Chem. Phys., 1986, 85, 6928. [all data]

Lew and Groleau, 1987
Lew, H.; Groleau, R., Electronic spectrum of D, Can. J. Phys., 1987, 65, 7, 739, https://doi.org/10.1139/p87-108 . [all data]

Gan, Yang, et al., 2004
Gan, Y.; Yang, X.; Guo, Y.; Wu, S.; Li, W.; Liu, Y.; Chen, Y., The absorption spectra of H, Mol. Phys., 2004, 102, 6, 611, https://doi.org/10.1080/00268970410001687425 . [all data]

Forney, Jacox, et al., 1993
Forney, D.; Jacox, M.E.; Thompson, W.E., The vibrational spectra of molecular ions isolated in solid neon. X. H2O+, HDO+, and D2O+, J. Chem. Phys., 1993, 98, 2, 841, https://doi.org/10.1063/1.464248 . [all data]

Zhou, Yang, et al., 2005
Zhou, H.; Yang, R.; Jin, X.; Zhou, M., Infrared Spectra of the OH, J. Phys. Chem. A, 2005, 109, 27, 6003, https://doi.org/10.1021/jp0511808 . [all data]

Duan, Zheng, et al., 2008
Duan, C.; Zheng, R.; Li, S.; Wang, R.; Huang, G., Infrared laser spectroscopy of the ν2 fundamental band of D2O+, J. Mol. Spectrosc., 2008, 251, 1-2, 22, https://doi.org/10.1016/j.jms.2008.01.004 . [all data]

Notes

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