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AsD2


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 19908.93 gas A-X 390 670 Dixon, Duxbury, et al., 1968
Grimminger and Clouthier, 2012


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 Bend 615.9 gas AB Dixon, Duxbury, et al., 1968

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 1511.4 gas LF Grimminger and Clouthier, 2012
2 Bend 704.7 gas LF Grimminger and Clouthier, 2012

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dixon, Duxbury, et al., 1968
Dixon, R.N.; Duxbury, G.; Lamberton, H.M., The Analysis of a FormulaAFormula-FormulaBFormula Electronic Band System of the AsHFormula and AsDFormula Radicals, Proc. Roy. Soc. (London) A305, 1968, 305, 1481, 271, https://doi.org/10.1098/rspa.1968.0118 . [all data]

Grimminger and Clouthier, 2012
Grimminger, R.A.; Clouthier, D.J., Toward an improved understanding of the AsH2 free radical: Laser spectroscopy, ab initio calculations, and normal coordinate analysis, J. Chem. Phys., 2012, 137, 22, 224307, https://doi.org/10.1063/1.4769778 . [all data]


Notes

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