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cyc-NiO2


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 8000 T gas Wu and Wang, 1997

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 OO stretch 968.4 Ne IR Allouti, Manceron, et al., 2006
1 OO stretch 967.1 s Ar IR Huber, Klotzbucher, et al., 1973
Citra, Chertihin, et al., 1997
Danset, Manceron, et al., 2001
1 OO stretch 970.1 N2 IR Citra, Chertihin, et al., 1997
2 ONiO s-stretch 541.6 Ne IR Allouti, Manceron, et al., 2006
2 NiO s-stretch 538.3 w Ar IR Citra, Chertihin, et al., 1997
Danset, Manceron, et al., 2001
b2 3 ONiO a-stretch 499.1 Ne IR Allouti, Manceron, et al., 2006
3 NiO a-stretch 511.7 m Ar IR Citra, Chertihin, et al., 1997
Danset, Manceron, et al., 2001

Additional references: Jacox, 1998, page 177; Jacox, 2003, page 107

Notes

wWeak
mMedium
sStrong
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wu and Wang, 1997
Wu, H.; Wang, L.-S., A Study of Nickel Monoxide (NiO), Nickel Dioxide (NiO2) and Ni(O2) Complex by Anion Photoelectron Spectroscopy, J. Chem. Phys., 1997, 107, 1, 16, https://doi.org/10.1063/1.474362 . [all data]

Allouti, Manceron, et al., 2006
Allouti, F.; Manceron, L.; Alikhani, M.E., The Ni + O2 reaction: A combined IR matrix isolation and theoretical study of the formation and structure of NiO2, Phys. Chem. Chem. Phys., 2006, 8, 4, 448, https://doi.org/10.1039/b513038g . [all data]

Huber, Klotzbucher, et al., 1973
Huber, H.; Klotzbucher, W.; Ozin, G.A.; Vander Voet, A., Binary Dioxygen Complexes of Nickel, Palladium, and Platinum, M(O, Can J. Chem., 1973, 51, 16, 2722, https://doi.org/10.1139/v73-408 . [all data]

Citra, Chertihin, et al., 1997
Citra, A.; Chertihin, G.V.; Andrews, L.; Neurock, M., Reactions of Laser-Ablated Nickel Atoms with Dioxygen. Infrared Spectra and Density Functional Calculations of Nickel Oxides NiO, ONiO, Ni, J. Phys. Chem. A, 1997, 101, 17, 3109, https://doi.org/10.1021/jp970019x . [all data]

Danset, Manceron, et al., 2001
Danset, D.; Manceron, L.; Andrews, L., Vibrational Spectra of Nickel and Platinum Dioxide Molecules Isolated in Solid Argon, J. Phys. Chem. A, 2001, 105, 30, 7205, https://doi.org/10.1021/jp010605x . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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