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NiNN


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 NN stretch 2089.2 vs Ar IR Ra Huber, Kundig, et al., 1973
Klotzbucher and Ozin, 1975
Andrews, Citra, et al., 1998
Manceron, Alikhani, et al., 1998
Pi 2 Bend 357.0 w Ar IR Manceron, Alikhani, et al., 1998
Sigma+ 3 NiN stretch 563.7 w m Ar IR Andrews, Citra, et al., 1998
Manceron, Alikhani, et al., 1998

Additional references: Jacox, 2003, page 73

Notes

wWeak
mMedium
vsVery strong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Huber, Kundig, et al., 1973
Huber, H.; Kundig, E.P.; Moskovits, M.; Ozin, G.A., Binary transition metal dinitrogen complexes. I. Matrix infrared and Raman spectra, structure and bonding of Ni(N2)n and Pd(N2)m(n = 1-4 and m = 1-3), J. Am. Chem. Soc., 1973, 95, 2, 332, https://doi.org/10.1021/ja00783a007 . [all data]

Klotzbucher and Ozin, 1975
Klotzbucher, W.; Ozin, G.A., Binary transition metal dinitrogen complexes. III. Metal-nitrogen stretching modes of Ni(N2)n, Pd(N2)m, and Pt(N2)m (where n = 1-4 and m = 1-3), J. Am. Chem. Soc., 1975, 97, 10, 2672, https://doi.org/10.1021/ja00843a014 . [all data]

Andrews, Citra, et al., 1998
Andrews, L.; Citra, A.; Chertihin, G.V.; Bare, W.D.; Neurock, M., Reactions of Laser-Ablated Co and Ni Atoms with Nitrogen Atoms and Molecules. Infrared Spectra and DFT Calculations of Metal Nitride Molecular Species and Complexes, J. Phys. Chem. A, 1998, 102, 15, 2561, https://doi.org/10.1021/jp9802836 . [all data]

Manceron, Alikhani, et al., 1998
Manceron, L.; Alikhani, M.E.; Joly, H.A., Infrared matrix isolation and DFT study of NiN2, Chem. Phys., 1998, 228, 1-3, 73, https://doi.org/10.1016/S0301-0104(97)00339-X . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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