OMnO


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   4B2


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 7340 ± 340 gas Gutsev, Rao, et al., 2000


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 260 ± 20 gas PE Gutsev, Rao, et al., 2000

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 800 ± 40 gas PE Gutsev, Rao, et al., 2000
1 Sym. stretch 816.4 Ar IR Chertihin and Andrews, 1997
b2 3 Asym. stretch 948.0 s Ar IR Serebrennikov and Maltsev, 1980
Chertihin and Andrews, 1997
3 Asym. stretch 969.6 N2 IR Chertihin and Andrews, 1997
3 Asym. stretch 962.4 N2 IR Chertihin and Andrews, 1997

Additional references: Jacox, 2003, page 105; Dong, Wang, et al., 2002

Notes

sStrong
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gutsev, Rao, et al., 2000
Gutsev, G.L.; Rao, B.K.; Jena, P.; Li, X.; Wang, L.-X., Experimental and theoretical study of the photoelectron spectra of MnO[sub x][sup -](x=1--3) clusters, J. Chem. Phys., 2000, 113, 4, 1473, https://doi.org/10.1063/1.481964 . [all data]

Chertihin and Andrews, 1997
Chertihin, G.V.; Andrews, L., Reactions of Laser-Ablated Manganese Atoms with Dioxygen. Infrared Spectra of MnO, OMnO, Mn(O, J. Phys. Chem. A, 1997, 101, 45, 8547, https://doi.org/10.1021/jp971813l . [all data]

Serebrennikov and Maltsev, 1980
Serebrennikov, L.V.; Maltsev, A.A., Vestn. Most. Univ., 1980, Ser. 2, Khim. 2, 148. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Dong, Wang, et al., 2002
Dong, J.; Wang, Y.; Zhou, M., The vibrational spectrum of the MnO2- and MnO4- anions in solid argon, Chem. Phys. Lett., 2002, 364, 5-6, 511, https://doi.org/10.1016/S0009-2614(02)01381-7 . [all data]


Notes

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