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GaGaH2


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 25000 T Ar Himmel, Manceron, et al., 2002
Himmel, Manceron, et al., 2002, 2

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 GaH2 s-stretch 1752.1 Ar IR Himmel, Manceron, et al., 2002
Himmel, Manceron, et al., 2002, 2
2 GaH2 scissors 752 Ar IR Himmel, Manceron, et al., 2002
Himmel, Manceron, et al., 2002, 2
b2 5 GaH2 a-stretch 1765.1 Ar IR Himmel, Manceron, et al., 2002
Himmel, Manceron, et al., 2002, 2

Notes

TTentative assignment or approximate value
dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Himmel, Manceron, et al., 2002
Himmel, H.-J.; Manceron, L.; Downs, A.J.; Pullumbi, P., Characterization and Photochemistry of the Gallium and Indium Subhydrides Ga2H2 and In2H2 This work was supported by the Deutsche Forschungsgemeinschaft (Habilitation grant to H.-J. H.), the CNRS (L. M.), and the EPSRC (A. J. D.)., Angew. Chem. Int. Ed., 2002, 41, 5, 796, https://doi.org/10.1002/1521-3773(20020301)41:5<796::AID-ANIE796>3.0.CO;2-3 . [all data]

Himmel, Manceron, et al., 2002, 2
Himmel, H.-J.; Manceron, L.; Downs, A.J.; Pullumbi, P., Formation and Characterization of the Gallium and Indium Subhydride Molecules Ga, J. Am. Chem. Soc., 2002, 124, 16, 4448, https://doi.org/10.1021/ja0122795 . [all data]


Notes

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