cyc-(FeO)2

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 3550 ± 400 gas Wu, Desai, et al., 1996

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
b2u 670 ± 70 gas PE Wu, Desai, et al., 1996
660.6 Ar IR Andrews, Chertihin, et al., 1996
Chertihin, Saffel, et al., 1996
Chertihin, Citra, et al., 1997
657.3 N2 IR Andrews, Chertihin, et al., 1996, 2
b3u 5 517.4 Ar IR Abramowitz, Acquista, et al., 1977
Chang, Blyholder, et al., 1981
Andrews, Chertihin, et al., 1996
Chertihin, Saffel, et al., 1996
5 535.5 N2 IR Andrews, Chertihin, et al., 1996, 2

Additional references: Jacox, 1998, page 244; Jacox, 2003, page 211

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wu, Desai, et al., 1996
Wu, H.; Desai, R.; Wang, L.-S., Observation and Photoelectron Spectroscopic Study of Novel Mono- and Di-iron Oxide Molecules: FeOy- (y=1-4) and Fe2Oy- (y=1-5), J. Am. Chem. Soc., 1996, 118, 22, 5296, https://doi.org/10.1021/ja954153b . [all data]

Andrews, Chertihin, et al., 1996
Andrews, L.; Chertihin, G.V.; Ricca, A.; Bauschlicher, C.W., Jr., Reactions of Laser-Ablated Iron Atoms with Oxygen Molecules: Matrix Infrared Spectra and Density Functional Calculations of OFeO, FeOO, and Fe(O, J. Am. Chem. Soc., 1996, 118, 2, 467, https://doi.org/10.1021/ja953338f . [all data]

Chertihin, Saffel, et al., 1996
Chertihin, G.V.; Saffel, W.; Yustein, J.T.; Andrews, L.; Neurock, M.; Ricca, A.; Bauschlicher, C.W., Jr., Reactions of Laser-Ablated Iron Atoms with Oxygen Molecules in Condensing Argon. Infrared Spectra and Density Functional Calculations of Iron Oxide Product Molecules, J. Phys. Chem., 1996, 100, 13, 5261, https://doi.org/10.1021/jp953198w . [all data]

Chertihin, Citra, et al., 1997
Chertihin, G.V.; Citra, A.; Andrews, L.; Bauschlicher, C.W., Jr., Reactions of Laser-Ablated Cobalt Atoms with O, J. Phys. Chem. A, 1997, 101, 47, 8793, https://doi.org/10.1021/jp972022m . [all data]

Andrews, Chertihin, et al., 1996, 2
Andrews, L.; Chertihin, G.V.; Citra, A.; Neurock, M., Reactions of Laser-Ablated Iron Atoms with N, J. Phys. Chem., 1996, 100, 27, 11235, https://doi.org/10.1021/jp960674p . [all data]

Abramowitz, Acquista, et al., 1977
Abramowitz, S.; Acquista, N.; Levin, I.W., Infrared spectra of matrix isolated FeO2: Evidence for a cyclic iron-oxygen complex, Chem. Phys. Lett., 1977, 50, 3, 423, https://doi.org/10.1016/0009-2614(77)80357-6 . [all data]

Chang, Blyholder, et al., 1981
Chang, S.; Blyholder, G.; Fernandez, J., Iron-oxygen interactions in an argon matrix, Inorg. Chem., 1981, 20, 9, 2813, https://doi.org/10.1021/ic50223a015 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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