Zn(C4H4N)


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 22253 gas B-X 420 466 Robles, Ellis, et al., 1992


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 8 Ring deform. 935 gas LF Robles, Ellis, et al., 1992
10 CH wag 819 gas LF Robles, Ellis, et al., 1992
11 Ring torsion 648 gas LF Robles, Ellis, et al., 1992
12 Zn..ring str. 278 gas LF Robles, Ellis, et al., 1992
13 Zn..ring bend 159 gas LF Robles, Ellis, et al., 1992
a 24 Zn..ring bend 127 H gas LF Robles, Ellis, et al., 1992

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 21733 gas A-X 437 460 Robles, Ellis, et al., 1992


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 12 Zn..ring str. 280 gas LF Robles, Ellis, et al., 1992
a 24 Zn..ring bend 131 H gas LF Robles, Ellis, et al., 1992

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 12 Zn..ring str. 257 gas LF Robles, Ellis, et al., 1992
13 Zn..ring bend 134 gas LF Robles, Ellis, et al., 1992
a 24 Zn..ring bend 119 H gas LF Robles, Ellis, et al., 1992

Additional references: Jacox, 1994, page 411

Notes

H(1/2)(2nu)
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Robles, Ellis, et al., 1992
Robles, E.S.J.; Ellis, A.M.; Miller, T.A., Electronic spectroscopy of jet-cooled half-sandwich organometallic free radicals. 2. Laser-induced fluorescence study of the pyrrolyl complexes of zinc and cadmium, J. Phys. Chem., 1992, 96, 8, 3258, https://doi.org/10.1021/j100187a016 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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