Cd(C4H4N)


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 22065 gas B-X 430 471 Robles, Ellis, et al., 1992


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 8 Ring deform. 925 gas LF Robles, Ellis, et al., 1992
10 CH wag 639 T gas LF Robles, Ellis, et al., 1992
11 Ring torsion 564 T gas LF Robles, Ellis, et al., 1992
12 Cd..ring str. 222 gas LF Robles, Ellis, et al., 1992
13 Cd..ring bend 151 gas LF Robles, Ellis, et al., 1992
a 24 Cd..ring bend 121 H gas LF Robles, Ellis, et al., 1992

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 21675 gas A-X 438 462 Robles, Ellis, et al., 1992


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 12 Cd..ring str. 225 gas LF Robles, Ellis, et al., 1992
a 24 Cd..ring bend 127 H gas LF Robles, Ellis, et al., 1992

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 12 Cd..ring str. 201 gas LF Robles, Ellis, et al., 1992
13 Cd..ring bend 121 gas LF Robles, Ellis, et al., 1992
a 24 Cd..ring bend 111 H gas LF Robles, Ellis, et al., 1992

Additional references: Jacox, 1994, page 412

Notes

H(1/2)(2nu)
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Robles, Ellis, et al., 1992
Robles, E.S.J.; Ellis, A.M.; Miller, T.A., Electronic spectroscopy of jet-cooled half-sandwich organometallic free radicals. 2. Laser-induced fluorescence study of the pyrrolyl complexes of zinc and cadmium, J. Phys. Chem., 1992, 96, 8, 3258, https://doi.org/10.1021/j100187a016 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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