HCCCCS


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 19980.69 gas A-X 470 510 Nakajima, Sumiyoshi, et al., 2002
Reilly, Cupitt, et al., 2006
Mazzotti, Achkasova, et al., 2008
Mazzotti, Chauhan, et al., 2008

State:   2Pi3/2


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 5 CS stretch 504 gas LF Nakajima, Sumiyoshi, et al., 2002
Reilly, Cupitt, et al., 2006

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 2 2007 gas LF Reilly, Cupitt, et al., 2006
3 1910 gas LF Reilly, Cupitt, et al., 2006
4 1077 T gas LF Reilly, Cupitt, et al., 2006
5 CS stretch 551 gas LF Reilly, Cupitt, et al., 2006

Additional references: Jacox, 1998, page 317; Hirahara, Ohshima, et al., 1994

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nakajima, Sumiyoshi, et al., 2002
Nakajima, M.; Sumiyoshi, Y.; Endo, Y., Laser induced fluorescence spectroscopy of the HC4S and DC4S radicals, Chem. Phys. Lett., 2002, 351, 5-6, 359, https://doi.org/10.1016/S0009-2614(01)01400-2 . [all data]

Reilly, Cupitt, et al., 2006
Reilly, N.J.; Cupitt, G.C.; Kable, S.H.; Schmidt, T.W., Experimental and theoretical investigation of the dispersed fluorescence spectroscopy of HC[sub 4]S, J. Chem. Phys., 2006, 124, 19, 194310, https://doi.org/10.1063/1.2196886 . [all data]

Mazzotti, Achkasova, et al., 2008
Mazzotti, F.J.; Achkasova, E.; Chauhan, R.; Tulej, M.; Radi, P.P.; Maier, J.P., Electronic spectra of radicals in a supersonic slit-jet discharge by degenerate and two-color four-wave mixing, Phys. Chem. Chem. Phys., 2008, 10, 1, 136, https://doi.org/10.1039/b712737e . [all data]

Mazzotti, Chauhan, et al., 2008
Mazzotti, F.J.; Chauhan, R.; Jamshidi, Z.; Tulej, M.; Radi, P.P.; Maier, J.P., The, Mol. Phys., 2008, 106, 24, 2709, https://doi.org/10.1080/00268970802656984 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Hirahara, Ohshima, et al., 1994
Hirahara, Y.; Ohshima, Y.; Endo, Y., Pulsed-discharge-nozzle Fourier-transform microwave spectroscopy of HC3S(2«PI»r) and HC4S(2«PI»i), J. Chem. Phys., 1994, 101, 9, 7342, https://doi.org/10.1063/1.468292 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References