cyc-ScC3

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 3390 ± 160 gas Wang and Li, 2000
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 CScC s-stretch 600 ± 50 gas PE Wang and Li, 2000

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 C3 s-stretch 1190.7 Ar IR Kinzer, Rittby, et al., 2008
3 CScC s-stretch 560 ± 30 gas PE Wang and Li, 2000
3 CScC s-stretch 557.0 Ar IR Kinzer, Rittby, et al., 2008
b2 5 C3 a-stretch 1478.0 Ar IR Kinzer, Rittby, et al., 2008

Additional references: Jacox, 2003, page 202

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang and Li, 2000
Wang, L.-S.; Li, X., Vibrationally resolved photoelectron spectroscopy of the first row transition metal and C[sub 3] clusters: MC[sub 3][sup -] (M=Sc, V, Cr, Mn, Fe, Co, and Ni), J. Chem. Phys., 2000, 112, 8, 3602, https://doi.org/10.1063/1.480513 . [all data]

Kinzer, Rittby, et al., 2008
Kinzer, R.E., Jr.; Rittby, C.M.L.; Graham, W.R.M., Fourier transform infrared observation of the ν[sub 3](σ[sub u]) vibration of NiC[sub 3]Ni in solid Ar, J. Chem. Phys., 2008, 128, 6, 064312, https://doi.org/10.1063/1.2827460 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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